32363-47-6

Basic information

• Product Name: Methanone, [4-(1,1-dimethylethyl)phenyl](2,4,6-trimethylphenyl)-
• CAS NO: 32363-47-6
• Molecular Formula: C20H24O
• Molecular Weight: 280.41
• Mol File: 32363-47-6.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Methanone, [4-(1,1-dimethylethyl)phenyl](2,4,6-trimethylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Methanone, [4-(1,1-dimethylethyl)phenyl](2,4,6-trimethylphenyl)-(32363-47-6)
• EPA Substance Registry System: Methanone, [4-(1,1-dimethylethyl)phenyl](2,4,6-trimethylphenyl)-(32363-47-6)

Safety Data

• Hazardous Substances Data: 32363-47-6(Hazardous Substances Data)

Upstream product

• 26537-19-9 methyl 4-tert-butylbenzoate 
• 108-67-8 1,3,5-trimethyl-benzene 
• 100-07-2 4-methoxy-benzoyl chloride 
• 954-16-5 2,4,6-Trimethylbenzophenon 
• 677-22-5 tert-butylmagnesium chloride 
• 594-19-4 tert.-butyl lithium 
• 1710-98-1 p-tert-butyl benzoyl chloride 
• 1150-51-2 (2,4,6-trimethylphenyl)(4-methoxyphenyl)methanone 

Relevant articles and documents

Iodine Promoted Conversion of Esters to Nitriles and Ketones under Metal-Free Conditions

We report a novel strategy to prepare valuable nitriles and ketones through the conversion of esters under metal-free conditions. By using the I2/PCl3 system, various substrates including aliphatic and aromatic esters could react with acetonitrile and arenes to afford the desired products in good to excellent yields. This method is compatible with a number of functional groups and provides a simple and practical approach for the synthesis of nitrile compounds and aryl ketones.

Ring tert-butylation of benzophenones and benzaldehyde with tert-butyllithium and thionyl chloride

One-flask ring tert-butylation of benzophenones and benzaldehyde with tert-butyllithium and thionyl chloride is reported. The scope of the reaction and the suggested mechanism are discussed.