71445-65-3Relevant academic research and scientific papers
Investigation of 1,4-elimination reactions of γ-trimethylsilyl alcohols via ionic and radical processes
Hwu, Jih Ru,Gilbert, Bryant A.
, p. 53 - 62 (1987)
Oxidative fragmentation of γ-trimethylsilyl alcohols with cerium ammonium nitrate occurs rapidly via a radical processes to provide keto olefins.Attempts to obtain the same products via an ionic type 1,4-elimination with the trimethylsilyl group as the directing moiety proved unsuccesful, even under a variety of harsh experimental conditions.Instead, dehydration products were produced in certain cases.
