32379-43-4Relevant academic research and scientific papers
A convenient one-pot synthesis of ketone cyanohydrin esters in aqueous media
Wet-Osot, Sirawit,Pattarawarapan, Mookda,Phakhodee, Wong
supporting information, p. 7172 - 7175 (2015/12/12)
A convenient one-pot, two-step procedure for the synthesis of ketone cyanohydrin esters in aqueous media is reported using N-acylbenzotriazoles as the acylating agents. In saturated aqueous sodium bicarbonate containing a catalytic amount of tetrabutylamm
DBU catalyzed cyanoacylation of ketones with acyl cyanides
Zhang, Wen,Shi, Min
, p. 1671 - 1674 (2008/02/11)
The reaction of cyclohexanone with benzoyl cyanide by amines provides the corresponding O-benzoyl cyanohedrin adducts in moderate to good yields under mild conditions. DBU was found to be the most effective promoter among the catalyst, allowing the reacti
An efficient and facile one-pot synthesis of cyanohydrin esters from carbonyl compounds catalyzed by iron(III) chloride
Iwanami, Katsuyuki,Aoyagi, Masaru,Oriyama, Takeshi
, p. 7487 - 7490 (2007/10/03)
A variety of cyanohydrin esters were readily prepared from carbonyl compounds with trimethylsilyl cyanide and acid anhydride under the influence of a catalytic amount of iron(III) chloride in a convenient one-pot procedure.
CROWN ETHER CATALYSIS IN THE SYNTHESIS OF CYANOHYDRIN DERIVATIVES
Chenevert, Robert,Plante, Raymond,Voyer, Normand
, p. 403 - 410 (2007/10/02)
Carbonyl compounds react with cyanide ion under phase transfer catalysis (18-crown-6) to give cyanohydrin anions which are trapped by acid chlorides, anhydrides or alkylating agents to give cyanohydrin derivatives.
