32390-14-0Relevant academic research and scientific papers
Photochemistry of Stable Free Radicals: The Photolysis of Perchlorotriphenylmethyl Radicals
Fox, Marye Anne,Gaillard, Elizabeth,Chen, Chia-Chung
, p. 7088 - 7094 (1987)
The excitation of perchlorotriphenylmethyl radical (PTM) at 532 nm leads to an excited doublet, 2PTM* (τ = 7 ns).The lifetime of this state is insensitive to oxygen, electron acceptors, and hydrogen-donating solvents.Electron donors
Inert Carbon Free Radicals. 5. Perchloro-9-phenylfluorenyl Radical Series
Ballester, M.,Castaner, J.,Riera, J.,Pujadas, J.,Armet, O.,et al.
, p. 770 - 778 (2007/10/02)
The synthesis of the perchloro-9-phenylfluorenyl radical (PPF) from 9-phenylfluorene (1) has been accomplished through a chlorolytic aromatic perchlorination to αH-pentadecachloro-2-biphenylylphenylmethane (2) with BMC reagent, followed by a cyclization a
Inert Carbon Free Radicals. 6. Perchloro-2-phenyldiphenylmethyl (PODM), a New Radical of the Perchlorodiphenylmethyl Series, and Products Therefrom
Ballester, M.,Castaner, J.,Riera, J.,Pujadas, J.
, p. 2884 - 2887 (2007/10/02)
In order to determine the effect of replacing an o-chlorine with a bulky pentachlorophenyl group on the stability of the perchlorodiphenylmethyl radical (PDM), a new perchlorinated radical, perchloro-2-phenyldiphenylmethyl (PODM), was examined.PODM was sy
