88180-06-7Relevant academic research and scientific papers
Inert Carbon Free Radicals. 10. Chlorination of Perchlorotriphenylmethyl (PTM) Radical. Synthesis, Structure, and Reactivity of Perchloro(diphenylmethylene)cyclohexa-1,4-diene
Ballester, M.,Riera, J.,Castaner, J.,Carreras, C.,Ubierna, J. J.,et al.
, p. 4611 - 4615 (2007/10/02)
Perchlorotriphenylmethyl radical (PTM-radical) is the paradigm of the chlorine-shielded "inert free radicals" (IFRs), which owe their unique chemical inertia to the colossal overcrowding about their trivalent carbon.However, they are active in single elec
Inert Carbon Free Radicals. 5. Perchloro-9-phenylfluorenyl Radical Series
Ballester, M.,Castaner, J.,Riera, J.,Pujadas, J.,Armet, O.,et al.
, p. 770 - 778 (2007/10/02)
The synthesis of the perchloro-9-phenylfluorenyl radical (PPF) from 9-phenylfluorene (1) has been accomplished through a chlorolytic aromatic perchlorination to αH-pentadecachloro-2-biphenylylphenylmethane (2) with BMC reagent, followed by a cyclization a
