4070-01-3Relevant academic research and scientific papers
Free Radicals as Clathrate Hosts: Crystal and Molecular Structure of 1:1 Perchlorotriphenylmethyl Radical-Benzene
Veciana, Jaume,Carilla, Josep,Miravitlles, Carlos,Molins, Elies
, p. 812 - 814 (1987)
The perchlorotriphenylmethyl radical (2) acts as a clathrate host forbenzene, halogenobenzenes, and 1,4-dioxane giving inclusion compounds with different stabilities; the structure of (2)-C6H6, established by X-ray diffraction, shows the guest molecules l
Chemical Modification toward Long Spin Lifetimes in Organic Conjugated Radicals
Dai, Ya-Zhong,Dong, Bo-Wei,Kao, Yi,Wang, Zi-Yuan,Un, Hio-Ieng,Liu, Zheng,Lin, Zhi-Jun,Li, Liang,Xie, Fang-Bai,Lu, Yang,Xu, Mei-Xing,Lei, Ting,Sun, Yu-Jie,Wang, Jie-Yu,Gao, Song,Jiang, Shang-Da,Pei, Jian
, p. 2972 - 2977 (2018/09/25)
Organic semiconductors for spin-based devices require long spin relaxation times. Understanding their spin relaxation mechanisms is critical to organic spintronic devices and applications for quantum information processing. However, reports on the spin re
Oxidation of the perchlorotriphenylmethyl radical to the carbocation, and its unique abrupt reversion
Ballester, Manuel,Miravitlles, Carlos,Molins, Elies,Carreras, Conxita
, p. 2748 - 2751 (2007/10/03)
A solution of AlCl3 in CH2Cl2 reacts slowly, at room temperature, with perchlorotriphenylmethyl radical (PTM.), an inert carbon free radical, to give perchlorotriphenylmethyl cation (PTM+) quantitativ
"Spin-Charge Exchange" in Allodial Radical Ions, a Novel Intramolecular Single Electron Transfer Equilibrium
Ballester, Manuel,Pascual, Isabel,Riera, Juan,Castaner, Juan
, p. 217 - 225 (2007/10/02)
The intramolecular single-electron transfer in radical anions and radical cations, constituted by two identical triphenylmethyl moieties, has been studied.The preparation of the radical ions has been effected by mixing the corresponding stable diions (tet
Unique Single-Electron Transfers between Chemically Inert Triphenylmethyl Radicals and Triphenylmethyl Anions
Ballester, Manuel,Pascual, Isabel,Torres, Josep
, p. 3035 - 3044 (2007/10/02)
A number of SET reactions between inert 4-X-tetradecachlorotriphenylmethyl radicals (X-PTM.) and stable tetra-n-butylammonium (Q+) 4-Y-tetradecachlorotriphenylmethides (Q+ Y-PTM:-; X,Y= H, Me, NH2CO, Me2NCO, Ph2
Inert Carbon Free Radicals. 10. Chlorination of Perchlorotriphenylmethyl (PTM) Radical. Synthesis, Structure, and Reactivity of Perchloro(diphenylmethylene)cyclohexa-1,4-diene
Ballester, M.,Riera, J.,Castaner, J.,Carreras, C.,Ubierna, J. J.,et al.
, p. 4611 - 4615 (2007/10/02)
Perchlorotriphenylmethyl radical (PTM-radical) is the paradigm of the chlorine-shielded "inert free radicals" (IFRs), which owe their unique chemical inertia to the colossal overcrowding about their trivalent carbon.However, they are active in single elec
Inert Carbon Free Radicals. 8. Polychlorotriphenylmethyl Radicals. Synthesis, Structure, and Spin-Density Distribution
Armet, O.,Veciana, J.,Rovira, C.,Riera, J,Castaner, J.,et al.
, p. 5608 - 5616 (2007/10/02)
Some symmetrical Ar3C. and unsymmetrical (C6Cl5)3-xArxC. radicals with different chlorine substitution patterns (X = 1,2; Ar: 2H-C6HCl4, 3H,5H-C6H2Cl4, 4H-C6HCl4, C6H5) are prepared.X-ray crystal structures for
SYNTHESIS AND PROPERTIES OF THE 1/1 COMPLEX OF 1,4,7,10,13,16-HEXAOXACYCLOOCTADECANE WITH POTASSIUM PERCHLOROTRIPHENYLMETHIDE
Veciana, J.,Riera, J.,Castaner, J.,Ferrer, N.
, p. 131 - 142 (2007/10/02)
The 1/1 complex of 1,4,7,10,13,16-hexaoxacyclooctadecane with potassium perchlorotriphenylmethide has been prepared by reaction, in the presence of 18-crown-6, of (C6Cl5)3CH with KOH or reduction of radical (C6Cl5)3 with K metal.Its structure as reveal
Inert Carbon Free Radicals. 2. Monofunctionalized Tetradecachlorotriphenylmethyl Radicals and Related Compounds
Ballester, M.,Castaner, J.,Riera, J.,Ibanez, A.,Pujadas, J.
, p. 259 - 264 (2007/10/02)
Perchlorinated triphenylmethyl radicals, and their nonradical α-H precursors, with hydrogen (2), carboxy (3), carbomethoxy (4), ammonium carboxylate (5), bromo (6), iodo (7), and methyl (8) substituents in the 4-position have been synthesized and their re
