32511-34-5

Basic information

• Product Name: (R)-(+)-BORNYLAMINE
• Synonyms: (R)-(+)-BORNYLAMINE;BORNANAMINE;ENDO-(1R)-1,7,7-TRIMETHYL-BICYCLO[2.2.1]HEPTAN-2-AMINE;(1R,2S,4R)-born-2-ylamine;(+)-Bornanamine, endo-(1R)-1,7,7-Trimethylbicyclo[2.2.1]heptan-2-amine;(1R,2S,4R)-1,7,7-Trimethylbicyclo[2.2.1]heptane-2-amine;(1R,4R,6S)-6α-Aminobornane;(6S)-1-Methyl-1β,4β-(isopropylidene)cyclohexane-6α-amine
• CAS NO: 32511-34-5
• Molecular Formula: C₁₀H₁₉N
• Molecular Weight: 153.26
• EINECS: 251-076-9
• Mol File: 32511-34-5.mol
• Article Data: 9

Chemical Properties

• Melting Point: 160-163 °C(lit.)
• Boiling Point: 189 ºC
• Flash Point: 48 ºC
• Appearance: White to off-white/Powder or Waxy Solid
• Density: 0.923
• Vapor Pressure: 0.591mmHg at 25°C
• Refractive Index: 1.4600 (estimate)
• Storage Temp.: 2-8°C
• PKA: 11.01±0.60(Predicted)
• BRN: 2801831
• CAS DataBase Reference: (R)-(+)-BORNYLAMINE(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(+)-BORNYLAMINE(32511-34-5)
• EPA Substance Registry System: (R)-(+)-BORNYLAMINE(32511-34-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• RIDADR: 3259
• WGK Germany: 3
• F: 10-34
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 32511-34-5(Hazardous Substances Data)

Usage

Chemical Properties

White crystal

General Description

(R)-(+)-Bornylamine in the presence of acetonitrile as a solvent and tetraethylammonium bromide as the bromide ion source, may be used in the crystallization-induced chiral inversion of (S)-2-bromo-3-phenylpropanoic acid to its (R)-enantiomer. It may also be used to synthesize trans-bis{(R)-(+)-bornylamino}palladium(II) dichloride, a palladium(II) complex with potent antitumor activity.

InChI:InChI=1/C10H19N/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7-8H,4-6,11H2,1-3H3/t7-,8+,10+/m1/s1

Upstream product

• 2792-42-9 (R,R)-camphor oxime 
• 37850-13-8 (1R,E)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one oxime 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 
• 540-69-2 ammonium formate 
• 7732-18-5 water 
• 464-48-2 (1S)-camphor 
• 78098-24-5 (1R,4R)-1,7,7-[2.2.1]heptan-2-one O-methyloxime 
• 464-43-7 d-borneol 
• 64-17-5 ethanol 
• 6535-09-7 (-)-2exo-bromo-2endo-nitro-bornane 
• 71-41-0 pentan-1-ol 
• 2792-42-9 camphor oxime 
• 77287-34-4 formamide 
• 76-22-2 Camphor 

Downstream Products

• 101599-01-3 N-((1R)-bornyl)-salicylamide 
• 464-17-5 (-)-bornylene 
• 464-49-3 (1R,4R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one 

Relevant articles and documents

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