3255-05-8Relevant academic research and scientific papers
Practical method for the preparation of nitrate esters
Hwu,Vyas,Patel,Lin,Yang
, p. 471 - 473 (1994)
A new and cost-effective method was developed for the preparation of nitrate esters in 67-92% yields from the corresponding alkyl toluenesulfonates and sodium nitrate with a catalytic amount of tetrabutylammonium nitrate in benzene and water at 110-135°C in a sealed tube.
A convenient and simple procedure for the preparation of nitrate esters from alcohols employing LiNO3/(CF3CO)2O
Gavrila, Adina,Andersen, Lisbeth,Skrydstrup, Troels
, p. 6205 - 6207 (2005)
Alcohols in small peptides, monosaccharides and steroids (12 examples) are conveniently transformed to their corresponding nitrate esters upon treatment with an acetonitrile solution of LiNO3 and trifluoroacetic anhydride. The in situ formed mi
A New Method for Selective Conversion of Alcohols to Nitrates under Mild and Neutral Conditions
Froeyen, Paul
, p. 89 - 98 (2007/10/03)
Treatment of alcohols with triphenylphosphine, N-bromosuccinimide (a positive halogen source), and silver nitrate affords the corresponding alkyl nitrates in excellent yields. - Keywords: Alkyl nitrates; alkoxyphosphonium salts; triphenylphosphine; N-bromosuccinimide; alcohols; Selective replacement of hydroxy groups by nitrate groups
Nitration by zinc nitrate: Preparation of nitrate ester of alcohol using zinc nitrate-dicyclohexyl carbodiimide combination
Sarma, Jadab C.
, p. 790 - 791 (2007/10/03)
A mild and selective method of preparation of nitrate ester from alcohol using the reagent combination of zinc nitrate and dicyclohexyl carbodiimide is reported here.
New one-pot synthesis of alkyl nitrates from alcohols
Castedo,Marcos,Monteagudo,Tojo
, p. 677 - 681 (2007/10/02)
Treatment of alcohols with Ph3P-I2-imidazole followed by 'in situ' reaction of the generated iodides with AgNO3 allows the mild conversion of alcohols into alkyl nitrates. Unlike previous procedures, this one requires no electrophilic nitrating conditions.
