327603-72-5

Upstream product

• 131087-35-9 phenyl 2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside 
• 333-27-7 methyl trifluoromethanesulfonate 
• 327603-48-5 phenyl 4-O-methyl-2,3-O-thionocarbonyl-1-thio-α-L-rhamnopyranoside 
• 327603-45-2 phenyl 4-O-methyl-1-thio-α-L-rhamnopyranoside 

Downstream Products

• 327603-81-6 phenyl 3-O-(methylthio)carbonyl-4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-thionocarbonyl-1-thio-α-L-rhamnopyranoside 
• 327603-93-0 Thiocarbonic acid O-[(2R,3S,4R,5S,6S)-2-((2S,3R,4S,5R,6S)-4,5-dihydroxy-2-methyl-6-phenylsulfanyl-tetrahydro-pyran-3-yloxy)-5-methoxy-6-methyl-3-phenylsulfanyl-tetrahydro-pyran-4-yl] ester S-methyl ester 
• 327603-85-0 phenyl 4-O-methyl-2-S-phenyl-2,6-di-deoxy-β-L-glucopyranosyl-(1->4)-2,3-O-isopropylidene-1-thio-α-L-rhamnopyranoside 

Relevant academic research and scientific papers

Recent advances in the synthesis of 2-deoxy-glycosides

Glycosides of 2-deoxy-sugars, monosaccharides in which the hydroxyl group at C-2 is replaced with a hydrogen atom, occur widely in natural products and therefore have been the subject of intense synthetic activity. The report summarizes recent advances in this area, with a particular focus on work published since an earlier review on the topic, in 2000 (Marzabadi, C. H.; Franck, R. W. Tetrahedron 2000, 56, 8385-8417).

Stereoselective synthesis of 2-S-phenyl-2-deoxy-beta-glycosides using phenyl 2,3-O-thionocarbonyl-1-thioglycoside donors via 1,2-Migration and concurrent glycosidation.

[figure: see text] 1,2-Migration and concurrent glycosidation of phenyl 2,3-O-thionocarbonyl-1-thlo-alpha-L-rhamnopyranosides under the action of methyl trifluoromethanesulfonate (MeOTf) afforded in high yields the 3-O-(methylthio)carbonyl-2-S-phenyl-2,6-