32799-32-9

Upstream product

• 17084-13-8 potassium hexafluorophosphate 
• 12257-42-0 [(norbornadiene)rhodium(I)chloride]2 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 

Downstream Products

• 32239-17-1 {Rh(As(CH₃)2C₆H₅)2(P(C₆H₅)3)2H₂}⁽¹⁺⁾*PF₆^(1-)={Rh(As(CH₃)2C₆H₅)2(P(C₆H₅)3)2H₂}PF₆ 
• 253120-26-2 RhH(P(C₆H₅)3)2((C₆H₅)2P(C₁₁H₁₃NO))⁽¹⁺⁾*PF₆^(1-)=[RhH(P(C₆H₅)3)2((C₆H₅)2P(C₁₁H₁₃NO))]PF₆ 
• 17374-65-1 {Rh((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2}⁽¹⁺⁾*PF₆^(1-)={Rh((C₆H₅)2PCH₂CH₂P(C₆H₅)2)2}PF₆ 
• 32354-99-7 {Rh(CH₃P(C₆H₅)2)4}⁽¹⁺⁾*PF₆^(1-)={Rh(CH₃P(C₆H₅)2)4}PF₆ 
• 32354-94-2 Rh(P(C₆H₅)(CH₃)2)4⁽¹⁺⁾*PF₆^(1-)=[Rh(P(C₆H₅)(CH₃)2)4]PF₆ 
• 47855-17-4 Rh(CO)3(P(C₆H₅)3)2⁽¹⁺⁾ 
• 78970-64-6 {Rh(P(C₆H₅)3)2H₂(CH₃CN)2}⁽¹⁺⁾*PF₆^(1-)={Rh(P(C₆H₅)3)2H₂(CH₃CN)2}PF₆ 
• 1092577-03-1 [Rh(H)(C₁₁H₈N)(P(C₆H₅)3)2(OC(CH₃)2)]⁽¹⁺⁾*PF₆^(1-)=[Rh(H)(C₁₁H₈N)(P(C₆H₅)3)2(OC(CH₃)2)]PF₆ 
• 1103534-52-6 [RhCl(C₁₃H₈N)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhCl(C₁₃H₈N)(P(C₆H₅)3)2]PF₆ 
• 1103534-58-2 [RhI(C₅H₄NC₆H₄)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhI(C₅H₄NC₆H₄)(P(C₆H₅)3)2]PF₆ 
• 1103534-61-7 Rh(C₁₁H₈N)I₂(P(C₆H₅)3)2 
• 1103534-54-8 [RhBr(C₁₃H₈N)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhBr(C₁₃H₈N)(P(C₆H₅)3)2]PF₆ 
• 1103534-59-3 Rh(C₁₃H₈N)Br₂(P(C₆H₅)3)2 
• 1103534-56-0 [RhBr(C₅H₄NC₆H₄)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhBr(C₅H₄NC₆H₄)(P(C₆H₅)3)2]PF₆ 

Relevant academic research and scientific papers

ORGANOMETALLIC MODELS FOR THE HYDRODESULPHURISATION (HDS) REACTION: SYNTHESIS OF + (M = Rh, Ir) AND X-RAY STRUCTURE OF THE Rh DERIVATIVE, THE FIRST EXAMPLE OF A FULLY CHARACTERISED ?-THIOPHENE COMPLEX OF AN HDS ACTIVE METAL

Hydrogenation of (M = Rh, Ir; NBD = norbornadiene) in CH2CL2/thiophene gives + (R = Rh, Ir) compounds, which have been isolated and characterised.In the case of + the structure has been determined by X-ray diffraction; the cation involves a trigonal arrangement of two phosphines and a ?-bonded thiophene around the Rh atom.Crystal data: triclinic, space group P1, a 11.774(6), b 18.083(8), c 11.425(5) Angstroem, α 75.24(2), β 105.48(2), γ 103.24(2) deg., U 2227(2) Angstroem3, and Z = 2.The coordinated thiophene is readily displaced by donor ligands from the Rh complex, but is strongly bound in the Ir analog.