(BICYCLO(2.2.1)HEPTA-2,5-DIENE)(BIS-(TRIPHENYLPHOSPHINE))RHODIUM (I) PF6

Base Information

• Chemical Name: (BICYCLO(2.2.1)HEPTA-2,5-DIENE)(BIS-(TRIPHENYLPHOSPHINE))RHODIUM (I) PF6
• CAS No.: 32799-32-9
• Molecular Weight: 862.58
• Mol file: 32799-32-9.mol

Synonyms:(BICYCLO(2.2.1)HEPTA-2,5-DIENE)(BIS-(TRIPHENYLPHOSPHINE))RHODIUM (I) PF6;bicycloheptadiene(bis(triphenylphosphine))rhodium(I) PF6

Chemical Property of (BICYCLO(2.2.1)HEPTA-2,5-DIENE)(BIS-(TRIPHENYLPHOSPHINE))RHODIUM (I) PF6

Chemical Property:

• PSA: 40.77000
• LogP: 10.99310

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (BICYCLO(2.2.1)HEPTA-2,5-DIENE)(BIS-(TRIPHENYLPHOSPHINE))RHODIUM (I) PF6

There total 2 articles about (BICYCLO(2.2.1)HEPTA-2,5-DIENE)(BIS-(TRIPHENYLPHOSPHINE))RHODIUM (I) PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

potassium hexafluorophosphate (17084-13-8) + [(norbornadiene)rhodium(I)chloride]2 (12257-42-0) → [Rh(norbornadiene)(PPh3)2](PF6) (32799-32-9)

Guidance literature:

With triphenylphosphine; In not given; react. of the rhodium complex with triphenylphosphine in the presence of KPF6 under inert atmosphere according to the method of Schrock, R. R. and Osborn, J. A., J. Amer. Chem. Soc. 93, 2397 (1971);

DOI:10.1016/0021-9517(83)90228-2

Reference yield:

{(η-thiophene)Rh(PPh3)2}{PF6}*2thiophene + bicyclo[2.2.1]hepta-2,5-diene (121-46-0) → [Rh(norbornadiene)(PPh3)2](PF6) (32799-32-9)

Guidance literature:

In dichloromethane; norbornadiene added to the soln. of Rh-compd. at 25°C;

DOI:10.1016/0022-328X(86)80512-5

Reference yield: 92.0%

2-(2-Bromophenyl)pyridine (109306-86-7) + [Rh(I)(norbornadiene)(PPh3)2]PF6 (32799-32-9) + hydrogen (1333-74-0) + acetone (67-64-1) → [RhBr(C5H4NC6H4)(P(C6H5)3)2](1+)*PF6(1-)=[RhBr(C5H4NC6H4)(P(C6H5)3)2]PF6 (1103534-56-0)

Guidance literature:

With tert-butylethylene; In acetone; (Schlenk); bubbling H2 through a suspn. of Rh complex in acetone for 15 min at 0°C, addn. of tert-butylethylene and ligand, stirring for 2 h at room temp.; filtration, washing ppt. with OEt2; elem. anal.;

DOI:10.1021/ic801878e

upstream raw materials:

potassium hexafluorophosphate

[(norbornadiene)rhodium(I)chloride]2

bicyclo[2.2.1]hepta-2,5-diene

Downstream raw materials:

[Rh(H)(C₁₃H₈N)(P(C₆H₅)3)2(OC(CH₃)2)]⁽¹⁺⁾*PF₆^(1-)=[Rh(H)(C₁₃H₈N)(P(C₆H₅)3)2(OC(CH₃)2)]PF₆

Rh(C₁₁H₈N)Br₂(P(C₆H₅)3)2

[RhBr(C₅H₄NC₆H₄)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhBr(C₅H₄NC₆H₄)(P(C₆H₅)3)2]PF₆

Rh(C₁₃H₈N)Br₂(P(C₆H₅)3)2