1103534-52-6

Basic information

• Product Name: [RhCl(C₁₃H₈N)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhCl(C₁₃H₈N)(P(C₆H₅)3)2]PF₆
• Synonyms: [RhCl(C₁₃H₈N)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhCl(C₁₃H₈N)(P(C₆H₅)3)2]PF₆
• CAS NO: 1103534-52-6
• Molecular Weight: 986.118
• Mol File: 1103534-52-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [RhCl(C₁₃H₈N)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhCl(C₁₃H₈N)(P(C₆H₅)3)2]PF₆(CAS DataBase Reference)
• NIST Chemistry Reference: [RhCl(C₁₃H₈N)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhCl(C₁₃H₈N)(P(C₆H₅)3)2]PF₆(1103534-52-6)
• EPA Substance Registry System: [RhCl(C₁₃H₈N)(P(C₆H₅)3)2]⁽¹⁺⁾*PF₆^(1-)=[RhCl(C₁₃H₈N)(P(C₆H₅)3)2]PF₆(1103534-52-6)

Safety Data

• Hazardous Substances Data: 1103534-52-6(Hazardous Substances Data)

Upstream product

• 408328-57-4 10-chlorobenzo[h]nquinoline 
• 32799-32-9 [Rh(I)(norbornadiene)(PPh₃)2]PF₆ 
• 1333-74-0 hydrogen 
• 67-64-1 acetone 

Relevant articles and documents

Chelation-assisted carbon-halogen bond activation by a rhodium(I) complex

Chelation-assisted activation of C-X bonds (X = Cl, Br, and I) took place in the reaction of [Rh(PPh3)2(acetone)2] + and 2-(2-halophenyl)pyridine or 10-halobenzo[h]quinoline. A series of 16-electron five-coordinate cationic rhodium(III) monohalide complexes was synthesized at room temperature. Neutral octahedral rhodium(III) dihalide complexes were obtained when the corresponding cationic monohalide complexes were further heated in acetone. Rhodium and iridium diiodides with these cyclometalation motifs could be alternatively synthesized from the reaction of the corresponding cyclometalated hydride complexes and I2. X-ray crystal structures of representative monohalide and dihalide complexes are reported. Octahedral rhodium(III) dihalide complexes are active catalysts for the dimerization of terminal alkynes, while 16-electron cationic rhodium(III) monohalides are inactive.