32812-90-1 Usage
Uses
Used in Chemical Synthesis:
(4-methyl)thiophenolato-lead(II) is used as a starting material for the synthesis of various lead-containing coordination compounds and organometallic complexes. Its unique structure and properties make it a valuable precursor in the development of new chemical compounds with specific applications.
Used in Catalysis:
In the field of catalysis, (4-methyl)thiophenolato-lead(II) is used as a component in the preparation of lead-based materials. These materials can act as catalysts in various chemical reactions, enhancing the reaction rates and improving the overall efficiency of the process.
Used in Materials Science:
(4-methyl)thiophenolato-lead(II) plays a role in the development of lead-based materials for applications in materials science. Its properties can contribute to the creation of materials with specific characteristics, such as improved electrical conductivity, mechanical strength, or thermal stability.
Used in Inorganic Chemistry:
(4-methyl)thiophenolato-lead(II) is also utilized in inorganic chemistry, where it can be employed in the study of metal coordination chemistry and the development of new inorganic compounds with potential applications in various industries.
Check Digit Verification of cas no
The CAS Registry Mumber 32812-90-1 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,2,8,1 and 2 respectively; the second part has 2 digits, 9 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 32812-90:
(7*3)+(6*2)+(5*8)+(4*1)+(3*2)+(2*9)+(1*0)=101
101 % 10 = 1
So 32812-90-1 is a valid CAS Registry Number.
32812-90-1Relevant academic research and scientific papers
Synthesis, Structure, and Catalytic Activity of μ-Alkylthio- and μ-Arylthio-μ-chloro-dicarbonylbis(tri-tert-butylphosphane)dirhodium Complexes
Schumann, Herbert,Cielusek, Guy,Jurgis, Stanislaw,Hahn, Ekkehardt,Pickardt, Joachim,et al.
, p. 2825 - 2838 (2007/10/02)
Tetracarbonyldi-μ-chloro-dirhodium (1) reacts with tri-tert-butylphosphane and alkyl or aryl trimethylsilyl sulfides 4 to give complexes tBu3)2Cl(SR)> (5a-i).The complexes 5h,i with the surface active trialkoxysilyl groups are fixed onto a fused silica support.The X-ray structural analyses of tBu3)2Cl(StBu)> (5c) and tBu3)2Cl(SC6H4Cl)> (5g) indicate a cis-configuration of the tri-tert-butylphosphane ligands.The new complexes catalyze the isomerization of 1-octen-3-ol (10) into 3-octanone (11), of 4-allylanisole (12) into cis- and trans-4-(1-propenyl)anisole (13), of trans-stilbene oxide (14) into desoxybenzoin (15), the transfer hydrogenation of α,β-unsaturated ketones by formic acid (16 -> 17), and the transfer hydrogenolysis of trihalomethyl compounds (18, 20) by halogen free alcohols.
