32819-62-8

Upstream product

• 87968-91-0 Toluene-4-sulfonic acid (1R,2R,4S,7S)-7-bromo-bicyclo[2.2.1]hept-2-yl ester 
• 87968-91-0 Toluene-4-sulfonic acid (1S,2R,4R,7R)-7-bromo-bicyclo[2.2.1]hept-2-yl ester 

Downstream Products

• 872171-93-2 (-)-(1S,4R,7S)-7-diphenylphosphino-2-phenylbicyclo[2.2.1]hept-2-ene 
• 872171-91-0 (1S,4R,7S)-7-(Diphenyl-phosphinoyl)-2-phenyl-bicyclo[2.2.1]hept-2-ene 
• 872171-90-9 (1S,4R,7S)-2-Benzyl-7-(diphenyl-phosphinoyl)-bicyclo[2.2.1]hept-2-ene 
• 865355-85-7 Trifluoro-methanesulfonic acid (1R,4S,7R)-7-(diphenyl-phosphinoyl)-bicyclo[2.2.1]hept-2-en-2-yl ester 
• 865355-86-8 (1R,4S,7R)-2-Benzyl-7-(diphenyl-phosphinoyl)-bicyclo[2.2.1]hept-2-ene 
• 865355-87-9 (1R,4S,7R)-7-(Diphenyl-phosphinoyl)-2-phenyl-bicyclo[2.2.1]hept-2-ene 
• 865355-81-3 (1R,4S,7R)-C₇H₈(phenyl)(P(phenyl)2) 
• 865355-84-6 (1R,4S,7R)-7-(Diphenyl-phosphinoyl)-bicyclo[2.2.1]heptan-2-one 

Relevant academic research and scientific papers

DIFFERENTIAL BRIDGING IN THE SOLVOLYSIS OF 6- AND 7-SUBSTITUTED 2-EXO- AND 2-ENDO-NORBORNYL p-TOLUENESULFONATES

The large difference between the reaction constants ρI for the solvolysis of the 6-exo- and 7-anti-substituted norbornyl tosylates 3 and 7, respectively, is further proof for the hypothesis that 2-norbornyl cations are anisotropic with regard to the transmission of polar effects and that through space induction involves graded bridging.