Tetrahedron Letters p. 3195 - 3198 (1983)
Update date:2022-07-29
Topics:
Flury, Peter
Grob, Cyril A.
The large difference between the reaction constants ρI for the solvolysis of the 6-exo- and 7-anti-substituted norbornyl tosylates 3 and 7, respectively, is further proof for the hypothesis that 2-norbornyl cations are anisotropic with regard to the transmission of polar effects and that through space induction involves graded bridging.
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