328404-66-6

Basic information

• Product Name: 1-Pyrrolidinecarboxylic acid, 3-hydroxy-2-[(1R)-1-(hydroxymethyl)-3-butenyl]-, phenylmethyl ester, (2R,3R)-
• CAS NO: 328404-66-6
• Molecular Formula: C17H23NO4
• Molecular Weight: 305.374
• Mol File: 328404-66-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1-Pyrrolidinecarboxylic acid, 3-hydroxy-2-[(1R)-1-(hydroxymethyl)-3-butenyl]-, phenylmethyl ester, (2R,3R)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Pyrrolidinecarboxylic acid, 3-hydroxy-2-[(1R)-1-(hydroxymethyl)-3-butenyl]-, phenylmethyl ester, (2R,3R)-(328404-66-6)
• EPA Substance Registry System: 1-Pyrrolidinecarboxylic acid, 3-hydroxy-2-[(1R)-1-(hydroxymethyl)-3-butenyl]-, phenylmethyl ester, (2R,3R)-(328404-66-6)

Safety Data

• Hazardous Substances Data: 328404-66-6(Hazardous Substances Data)

Upstream product

• 328404-64-4 (1R,4R,5R)-6-(benzyloxycarbonyl)-4-(3-propenyl)-6-aza-2-oxa-bicyclo[3.3.0]-3-octanone 
• 95456-65-8 (1R,5R)-(-)-6-aza-6-benzyloxycarbonyl-2-oxabicyclo[3.3.0]octan-3-one 
• 328404-56-4 (R)-3-[(1-bezyloxy-carbonyl)-pyrrolidinyl]-α-diazoacetate 
• 100858-33-1 (3R)-3-hydroxy-pyrrolidine-1-carboxylic acid benzyl ester 
• 501-53-1 benzyl chloroformate 

Downstream Products

• 328404-68-8 3-(tert-butyl-diphenyl-silanyloxy)-2-[1-(tert-butyl-diphenyl-silanyloxymethyl)-3-hydroxy-propyl]-pyrrolidine-1-carboxylic acid benzyl ester 
• 21850-67-9 (-)-turneforcidine 
• 328404-70-2 (1R,7R,8R)-7-(tert-butyldiphenylsilyloxy)-1-(tert-butyldimethylsilyloxymethyl)pyrrolizidine 
• 328404-69-9 3-(tert-butyl-diphenyl-silanyloxy)-2-[1-(tert-butyl-diphenyl-silanyloxymethyl)-3-methanesulfonyloxy-propyl]-pyrrolidine-1-carboxylic acid benzyl ester 
• 389874-45-7 3-(tert-butyl-diphenyl-silanyloxy)-2-[1-(tert-butyl-diphenyl-silanyloxymethyl)-but-3-enyl]-pyrrolidine-1-carboxylic acid benzyl ester 

Relevant articles and documents

A facile synthesis of (-)- and (+)-Geissman-Waiss lactone via intramolecular Rh(II)-carbenoid mediated C-H insertion reaction: Synthesis of (1R,7R,8R)-turneforcidine

The intramolecular C-H insertion reaction in chiral non-racemic diazoacetates (-)-6 and (+)-8 catalyzed by chiral Rh2(MPPIM)4 proceeded efficiently, with excellent regioselectivity and cis-diastereoselectivity, to give (-)- and (+)-G