32885-83-9Relevant academic research and scientific papers
A series of two oxidation reactions of ortho-alkenylbenzamide with hypervalent iodine(III): A concise entry into (3 R,4 R)-4-hydroxymellein and (3 R,4 R)-4-hydroxy-6-methoxymellein
Takesue, Takuya,Fujita, Morifumi,Sugimura, Takashi,Akutsu, Hiroki
supporting information, p. 4634 - 4637 (2015/01/09)
A sequence of oxidation reactions of alkenamides with hypervalent iodine is described. Oxidation of ortho-alkenylbenzamide substrates selectively gave isochroman-1-imine products. The products underwent further oxidation in the presence of a Pd salt catal
Asymmetric synthesis of 4,8-dihydroxyisochroman-1-one polyketide metabolites using chiral hypervalent iodine(III)
Fujita, Morifumi,Mori, Kazuhiro,Shimogaki, Mio,Sugimura, Takashi
, p. 1294 - 1297 (2012/05/31)
Stereoselective oxylactonization of ortho-alkenylbenzoate with chiral hypervalent iodine is applied to the asymmetric synthesis of 4-oxyisochroman-1-one polyketide metabolites including 4-hydroxymellein (1), a derivative of fusarentin 2, monocerin (3), and an epimer of monocerin epi-3.
