32907-85-0

Upstream product

• 536-74-3 phenylacetylene 
• 2603-10-3 N-phenyl methyl carbamate 
• 932-87-6 1-Bromo-2-phenylacetylene 

Downstream Products

• 1610846-87-1 methyl (2-oxo-2-phenylacetyl)(phenyl)carbamate 
• 1629962-39-5 methyl (E)-(1,2-dibromo-2-phenylvinyl)(phenyl)carbamate 
• 1629962-38-4 methyl (E)-(1,2-diiodo-2-phenylvinyl)(phenyl)carbamate 
• 1629962-29-3 methyl (E)-(1-bromo-2-iodo-2-phenylvinyl)(phenyl)carbamate 

Relevant academic research and scientific papers

Ruthenium-catalyzed [2 + 2] cycloadditions of ynamides

(Chemical Equation Presented) Ruthenium-catalyzed [2 + 2] cycloadditions between norbornene and ynamides were investigated. The ynamide moiety was found to be compatible with the ruthenium-catalyzed cycloaddition conditions, giving the corresponding cyclobutene cycloadducts in moderate to good yields (up to 97%).

(E)-1-BROMO-2-IODOENAMIDE DERIVATIVE OR SALT THEREOF, AND METHOD FOR PRODUCING (E)-1-BROMO-2-IODOENAMIDE DERIVATIVE OR SALT THEREOF

PROBLEM TO BE SOLVED: To provide a bromo-iodoenamide obtained by controlling position and stereoselectivity. SOLUTION: Provided is a (E)-1-bromo-2-iodoenamide derivative represented by the following chemical formula (I) or a salt thereof. (In the formula, A is an aromatic hydrocarbon group or a cyclic aliphatic hydrocarbon group, where the aromatic hydrocarbon group or the cyclic aliphatic hydrocarbon group may or may not have a substituent, where the substituent, when present in a plurality, may be the same or different; B and D, together with a nitrogen atom neighboring B and D, form a ring; or B is an electron withdrawing group, and D is a hydrogen atom or an aromatic hydrocarbon group or a cyclic aliphatic hydrocarbon group which may or may not have a substituent, where the substituent, when present in a plurality, may be the same or different.) COPYRIGHT: (C)2015,JPOandINPIT

Ruthenium-catalyzed [2 + 2] cycloadditions of bicyclic alkenes and ynamides

Ruthenium-catalyzed [2 + 2] cycloadditions between bicyclic alkenes and ynamides were investigated. The ynamide moiety was found to be compatible with the ruthenium-catalyzed cycloaddition conditions giving the corresponding cyclobutene cycloadducts in moderate to good yields (up to 97%). Diastereoselective cycloaddition utilizing chiral cyclic ynamides were also examined and a low to moderate level of asymmetric induction was observed.