329913-81-7

Basic information

• Product Name: (2R)-5-benzyloxy-2-methyl-1-pentanal
• Synonyms: (2R)-5-benzyloxy-2-methyl-1-pentanal
• CAS NO: 329913-81-7
• Molecular Weight: 206.285
• Mol File: 329913-81-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (2R)-5-benzyloxy-2-methyl-1-pentanal(CAS DataBase Reference)
• NIST Chemistry Reference: (2R)-5-benzyloxy-2-methyl-1-pentanal(329913-81-7)
• EPA Substance Registry System: (2R)-5-benzyloxy-2-methyl-1-pentanal(329913-81-7)

Safety Data

• Hazardous Substances Data: 329913-81-7(Hazardous Substances Data)

Upstream product

• 253882-47-2 (R)-4-benzyl-3-(5-benzyloxy-pentanoyl)oxazolidin-2-one 
• 4541-15-5 5-(benzyloxy)-1-pentanol 
• 100-39-0 benzyl bromide 
• 111-29-5 1 ,5-pentanediol 
• 329913-80-6 (R)-1-(tert-butyldimethylsilyl)oxy-2-methyl-5-benzyloxypentane 
• 329913-79-3 (R)-ethyl 5-(tert-butyldimethylsilyl)oxy-4-methyl-pentanoate 
• 143728-66-9 (R)-S₇₅-((tert-butyldimethylsilyl)oxy)-4-methylpentan-1-ol 
• 135212-08-7 (R,E)-ethyl 5-(tert-butyldimethylsilyl)oxy-4-methyl-2-pentenoate 
• 128329-72-6 5-(phenylmethoxy)pentanoic acid chloride 
• 81927-55-1 O-benzyl 2,2,2-trichloroacetimidate 
• 64740-39-2 5-benzyloxypentanoic acid 
• 329914-30-9 (4R,5S)-3-((R)-5-Benzyloxy-2-methyl-pentanoyl)-4-methyl-5-phenyl-oxazolidin-2-one 
• 329914-29-6 (4R,5S)-3-(5-Benzyloxy-pentanoyl)-4-methyl-5-phenyl-oxazolidin-2-one 
• 164907-39-5 (4R)-5-[1-(tert-butyl)-1,1-diphenylsilyl]oxy-4-methylpentan-1-ol 

Downstream Products

• 1427219-16-6 (6R)-9-benzyloxy-6-methylnon-4-enoic acid benzyl ester 
• 1427219-17-7 (6R)-9-benzyloxy-6-methylnon-4-enoic acid benzyl ester 
• 1159576-56-3 (4R,Z)-1-benzyloxy-4-methyl-5-octene 

Relevant articles and documents

Synthesis of the polyketide (E)-olefin of the jamaicamides

The jamaicamides, isolated in Jamaica from the cyanobacterium Lyngbya majuscula, are new mixed polyketide-peptides that are known to be sodium channel blockers. The polyketide moiety contains an (E)-vinyl chloride, an undetermined methyl stereocenter (C9), and an (E)-olefin. Herein, we report the synthesis of the (E)-olefin moiety of the polyketide of the jamaicamides utilizing a Kocienski-Julia coupling. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications to view the free supplemental file.

Total synthesis of halipeptins: Isolation of halipeptin D and synthesis of oxazoline halipeptin analogues

The isolation from the marine sponge Leiosella cf. arenifibrosa and structural elucidation of halipeptin D (5). a relative of the previously isolated halipeptins A-C (1-3), is described along with the total synthesis of a number of oxazoline analogues (7a