33070-25-6Relevant articles and documents
Reaction of polycyclic aromatic hydrocarbons adsorbed on silica in aqueous chlorine
Nakamura, Hideyuki,Tomonaga, Yuzo,Miyata, Kana,Uchida, Mitsuo,Terao, Yoshiyasu
, p. 2190 - 2195 (2007)
The reaction of polycyclic aromatic hydrocarbons (PAHs) previously adsorbed on silica gel or diatomaceous earth with sodium hypochlorite was carried out to elucidate their reactivity to aqueous chlorine. It was demonstrated that the PAHs adsorbed on silica reacted more rapidly than the PAHs themselves in water, leading to the formation of many chlorinated and oxidized derivatives. A similar reaction in the presence of potassium bromide was found to preferentially produce corresponding brominated derivatives. These reactions seem to proceed through PAHs adsorbed on the silica surface and halogenating agents, the electrophilicity of which may be raised by the catalytic effect of the silanol group of the silica surface. These findings from the environmental viewpoint suggest that the reaction of hydrophobic compounds adsorbed on sediment cannot be neglected.
