330983-72-7Relevant academic research and scientific papers
Co-catalyst dependent cycloisomerization or ring closing metathesis of α,ω-dienes catalyzed by arene ruthenium complex with side-arm alcohol
Miyaki, Yoshiharu,Onishi, Takafumi,Ogoshi, Sensuke,Kurosawa, Hideo
, p. 135 - 139 (2000)
Cycloisomerization and ring closing metathesis of some α,ω-dienes were catalyzed by a cationic arene ruthenium chelate complex [Ru{η6:η1-Ph(CH2) 3OH}(PCy3)Cl]BF4 (1a) in the presence of triethylamine and phenylacetylene, respectively, as co-catalysts. Analogous catalyst systems employing arene ruthenium cations without the side arm alcohol functional group showed lower efficiencies.
