331248-82-9

Upstream product

• 100-39-0 benzyl bromide 
• 331248-77-2 (E)-1-[[4-(5-methoxycarbonyl-2,3-diphenylmethylenedioxy)phenoxy]phenyl]-2-[2-bromo-4-benzyloxy-5-methoxyphenyl]ethene 
• 331248-68-1 methyl 4,5-diphenylmethylenedioxy-3-(4-formylphenoxy)benzoate 
• 331248-70-5 dimethyl 2-bromo-4-benzyloxy-5-methoxybenzylphosphonate 
• 222622-96-0 5-(benzyloxy)-1-bromo-2-(bromomethyl)-4-methoxybenzene 
• 65341-82-4 [4-(benzyloxy)-2-bromo-5-methoxyphenyl]methanol 
• 121-33-5 vanillin 
• 69829-46-5 methyl 7-hydroxy-2,2-diphenylbenzo[d]-1,3-dioxole-5-carboxylate 
• 40705-22-4 4-benzyloxy-6-bromo-3-methoxybenzaldehyde 
• 1700-37-4 3-Benzyloxybenzaldehyde 
• 2426-87-1 3-methoxy-4-(phenylmethoxy)benzaldehyde 
• 85604-06-4 5-(benzyloxy)-2-bromobenzaldehyde 
• 331248-79-4 (E)-1-[[4-(5-dimethylphosphonomethyl-2,3-diphenylmethylenedioxy)phenoxy]phenyl]-2-[2-bromo-4-benzyloxy-5-methoxyphenyl]ethene 

Relevant academic research and scientific papers

Total syntheses of plagiochins A and D, macrocyclic bis(bibenzyls), by Pd(0) catalyzed intramolecular Stille-Kelly reaction

Total syntheses of plagiochins A (1) and D (4), the former of which exhibits a significant neurotrophic activity, have been accomplished. The key 16-membered ring closure in 4 has been achieved directly from the dibromoperrottetin derivative (7) by Pd(0)

Versatile synthons for optically pure alpha-amino aldehydes and alpha-amino acids: (+)- and (-)-4,5-dialkoxy-2-oxazolidinones.

Both enantiomers of trans-5-benzyloxy-4-methoxy- (BMOx) and trans-4,5-dimethoxy-2-oxazolidinones (DMOx), which are readily accessible from simple 2-oxazolone heterocycles, represent good candidates for a new class of chiral synthons for use in the preparation of optically pure alpha-amino aldehydes and alpha-amino acids, respectively.