33214-70-9

Usage

Uses

Used in Chemical Industry:
1,2,3,4-tetrahydro-5-Methoxy-1,1-diMethylnaphthalene is used as a hydrogenation catalyst for promoting chemical reactions in the chemical industry. Its catalytic properties make it a valuable component in various chemical processes.
Used in Agriculture:
In the agricultural industry, 1,2,3,4-tetrahydro-5-Methoxy-1,1-diMethylnaphthalene is used as a component in the production of insecticides. Its ability to act as an insecticide helps in controlling pests and protecting crops.
Used in Solvent Applications:
1,2,3,4-tetrahydro-5-Methoxy-1,1-diMethylnaphthalene is used as a solvent for resins and waxes. Its solubility properties make it suitable for dissolving various substances, facilitating their use in different applications.
Used in Dyes and Perfumes:
In the formulation of dyes and perfumes, 1,2,3,4-tetrahydro-5-Methoxy-1,1-diMethylnaphthalene is used as a component. Its mild odor and chemical properties contribute to the creation of various fragrances and colorants.
However, it is important to note that 1,2,3,4-tetrahydro-5-Methoxy-1,1-diMethylnaphthalene may be harmful if inhaled or ingested, and can cause irritation to the skin and eyes. Proper handling and safety measures should be taken when working with this chemical compound.

InChI:InChI=1/C13H18O/c1-13(2)9-5-6-10-11(13)7-4-8-12(10)14-3/h4,7-8H,5-6,9H2,1-3H3

Upstream product

• 33209-77-7 2-Methyl-5-o-anisyl-2-pentanol 
• 171979-70-7 1-methoxy-2-(4-methylpent-3-en-1-yl)benzene 
• 2270-59-9 1-bromo-4-methylpent-3-ene 
• 578-57-4 2-bromoanisole 
• 100-66-3 methoxybenzene 
• 33209-76-6 Ethyl 4-(2-Methoxyphenyl)-butanoate 
• 108840-41-1 1-(2-methoxy-phenyl)-2-(toluene-4-sulfonyloxy)-ethane 
• 33209-75-5 4-(2-Methoxyphenyl)-butanoic acid 

Downstream Products

• 109664-02-0 5,6,7,8-tetrahydro-3-hydroxy-2-[(1R)-2-hydroxy-1-methylethyl]-8,8-dimethyl-1,4-phenanthrenedione 
• 35825-57-1 Cryptotanshinone 
• 568-72-9 tanshinone-IIA 

Relevant academic research and scientific papers

Antitumor agents 269. Non-aromatic ring-A neotanshinlactone analog, TNO, as a new class of potent antitumor agents

Tetrahydroneotanshinlactone (TNT) and tetrahydronaphthalene-1-ol (TNO) derivatives were designed, synthesized, and evaluated for cytotoxic activity. The TNO derivatives were found to be a promising novel class of in vitro antitumor agents. The cyclohexene

Biaromatic compounds and pharmaceutical and cosmetic compositions comprising them

Biaromatic compounds connected by a propynylene or ailenylene bond, corresponding to the formula (I).

Atomatic Annulation Strategy for the Synthesis of Angularly-Fused Diterpenoid Quinones. Total Synthesis of (+)-Neocryptotanshinone, (-)-Cryptotanshinone, Tanshinone IIA, and (+/-)-Royleanone

The application of a photochemical aromatic annulation strategy in highly efficient total syntheses of several diterpenoid quinones isolated from the traditional Chinese medicine Dan Chen is reported.The pivotal step in each synthesis involves the assembly of the key tricyclic intermediate via the application of a recently developed "second generation" photochemical aromatic annulation method for the construction of highly substituted aromatic systems.In the total synthesis of neocryptotanchinone, the synthesis of the requisite diazo ketone anulation substrate 7 was achieved using paladium-mediated coupling reactions and an intramolecular Friedel-Crafts cyclization to form key carbon-carbon bonds.The pivotal aromatic annulation reaction was then accomplished by irradiating a solution of the diazo ketone 7 and the readily availabe siloxyalkyne 6 in benzene at room temperature.The desired tricyclic phenol 16 was produced in 58-65percent yield and was then converted to (+)-neocryptotanshinone (1) by treatment with tetra-n-butylammonium fluoride in the presence of oxygen.Cyclization to generate (-)-cryptotanshinone (2) was accomplished in high yield by brief exposure of 1 to an ethanolic solution of concentrated sulfuric acid, and dehydrogenation of 2 with DDQ furnished tanshinone IIA (3).As a further demonstration of the utility of the photochemical aromatic annulation strategy in the construction of angularly-fused diterpenes, the total synthesis of (+/-)-royleanone (4) was also investigated.Irradiation of a solution of the diazo ketone 18 and siloxyalkyne 25 produced the tricyclic intermediate 26, which was converted in two steps to royleanone by desilylation and oxidation.