33288-21-0Relevant academic research and scientific papers
Synthesis of polyfluoroarylalkyl sulfide compounds
Ward, Wayne E.,Sicree, Stephen,Chen, Brian,Tamborski, Christ
, p. 73 - 78 (2007/10/02)
Syntheses of RC6F4SR' compounds (where R = F, C6H5, H, R' = alkyl, trifluorovinyl) have been accomplished through reaction between ArfSM (where M = Cu, MgX) and an alkyl or trifluorovinyl halide in dimethylacetamide solvent.Minor by-products from competing reactions have been partially characterized by GC-MS analysis. - Keywords: Synthesis; Polyfluoroalkyl sulfides; NMR spectroscopy; Mass spectrometry
Cleavage of pentafluorophenyl-phosphorus and -sulfur bonds by ethylmagnesium bromide
Sicree, Stephen A.,Tamborski, Christ
, p. 269 - 273 (2007/10/02)
Tris(pentafluorophenyl) phosphine and bis (pentafluorophenyl) sulfide react with ethylmagnesium bromide to give products indicating cleavage of the pentafluorophenyl group from phosphorus and sulfur.Ethylated phosphorus and sulfur compounds as well as pentafluorophenylmagnesium bromide are the principal reaction products.Minor products from subsequent reaction the Grignard reagents and cleavage products have also been detected.
SOME REACTIONS OF COPPER(I) PENTAFLUOROTHIOPHENOLATE
Peach, Michael E.,Ritcey, Anna M.
, p. 401 - 406 (2007/10/02)
Copper(I) pentafluorothiophenolate, CuSC6F5 reacted with a number of acyl and alkyl halides in either n-hexane or DMF.The products RCH2SC6F5 ( R = Me, Ph, C6F5S, C6F5SCH2), PH2CHSC6F5, R3CSC6F5 (R = Me, Ph) and RCOSC6F5 (R = Me, C6F5) have been characterized and their spectra, particularly NMR spectra (H-1, C-13, F-19) have been examined.
Partially Fluorinated Heterocyclic Compounds. Part 14. Syntheses of 4,5,6,7-Tetrafluoro-2,3-dihydro-2-methyl-1-benzothiophen and 5,6,7,8-Tetrafluorothiochroman from Pentafluorophenyl Prop-2-enyl Sulphide via the Claisen Rearrangement Intermediate and the
Brooke, Gerald M.,Wallis, Derek I.
, p. 1659 - 1664 (2007/10/02)
Prop-2-enyl 2,3,4,5-tetrafluorophenyl sulphide (1) undergoes a Claisen rearrangement in NN-diethylaniline to give 4,5,6,7-tetrafluoro-2,3-dihydro-2-methyl-1-benzothiophen (4) and 5,6,7,8-tetrafluorothiochroman (5).Pentafluorophenyl prop-2-enyl sulphide (3
