33288-21-0

Basic information

• Product Name: ethyl pentafluorophenyl sulphide
• Synonyms: ethyl pentafluorophenyl sulphide
• CAS NO: 33288-21-0
• Molecular Weight: 228.186
• Mol File: 33288-21-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: ethyl pentafluorophenyl sulphide(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl pentafluorophenyl sulphide(33288-21-0)
• EPA Substance Registry System: ethyl pentafluorophenyl sulphide(33288-21-0)

Safety Data

• Hazardous Substances Data: 33288-21-0(Hazardous Substances Data)

Upstream product

• 1043-50-1 pentafluorophenyl sulfide 
• 925-90-6 ethylmagnesium bromide 
• 70168-12-6 pentafluorophenyl-prop-2-enyl thioether 
• 771-62-0 pentafluorophenylthiol 
• 75-03-6 ethyl iodide 
• 13839-57-1 copper(I) pentafluorothiophenolate 
• 344-04-7 bromopentafluorobenzene 
• 51098-05-6 Methyl-dithiocarbamic acid pentafluorophenyl ester 
• 344-07-0 1-chloro-2,3,4,5,6-pentafluorobenzene 
• 40779-99-5 Lithium; 2,3,4,5,6-pentafluoro-benzenethiolate 
• 879-05-0 2,3,4,5,6-pentafluorophenylmagnesium bromide 
• 1076-44-4 pentafluorophenyl lithium 
• 392-56-3 Hexafluorobenzene 

Downstream Products

• 78453-51-7 trans-PtCl₂(C₆F₅SCH₂CH₃)2 

Relevant articles and documents

Synthesis of polyfluoroarylalkyl sulfide compounds

Syntheses of RC6F4SR' compounds (where R = F, C6H5, H, R' = alkyl, trifluorovinyl) have been accomplished through reaction between ArfSM (where M = Cu, MgX) and an alkyl or trifluorovinyl halide in dimethylacetamide solvent.Minor by-products from competing reactions have been partially characterized by GC-MS analysis. - Keywords: Synthesis; Polyfluoroalkyl sulfides; NMR spectroscopy; Mass spectrometry

SOME REACTIONS OF COPPER(I) PENTAFLUOROTHIOPHENOLATE

Copper(I) pentafluorothiophenolate, CuSC6F5 reacted with a number of acyl and alkyl halides in either n-hexane or DMF.The products RCH2SC6F5 ( R = Me, Ph, C6F5S, C6F5SCH2), PH2CHSC6F5, R3CSC6F5 (R = Me, Ph) and RCOSC6F5 (R = Me, C6F5) have been characterized and their spectra, particularly NMR spectra (H-1, C-13, F-19) have been examined.