33322-66-6

Basic information

• Product Name: Benzamide, 4-ethyl-N,N-dimethyl-
• CAS NO: 33322-66-6
• Molecular Formula: C11H15NO
• Molecular Weight: 177.246
• Mol File: 33322-66-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzamide, 4-ethyl-N,N-dimethyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzamide, 4-ethyl-N,N-dimethyl-(33322-66-6)
• EPA Substance Registry System: Benzamide, 4-ethyl-N,N-dimethyl-(33322-66-6)

Safety Data

• Hazardous Substances Data: 33322-66-6(Hazardous Substances Data)

Upstream product

• 7463-22-1 N,N-Dimethyl-p-chlorobenzenesulfonamide 
• 2386-64-3 ethylmagnesium chloride 
• 14062-80-7 N,N-dimethyl-4-chlorobenzamide 
• 16331-45-6 p-ethylbenzoyl chloride 
• 506-59-2 N,N-dimethylammonium chloride 

Downstream Products

• 1008119-09-2 4-acetyl-N,N-dimethylbenzamide 
• 1325242-73-6 4-(α-benzoyloxyethyl)-N,N-dimethylbenzamide 
• 1325242-78-1 4-(α-acetoxyethyl)-N-methylbenzamide 
• 1325242-68-9 4-(α-acetoxyethyl)-N,N-dimethylbenzamide 

Relevant articles and documents

Iron-Catalyzed C(sp2)-C(sp3) Cross-Coupling of Chlorobenzenesulfonamides with Alkyl Grignard Reagents: Entry to Alkylated Aromatics

Alkylated benzosulfonamides are compounds of high importance in organic synthesis, including the production of pharmaceuticals, agrochemicals, and plasticizers. We report the iron-catalyzed C(sp2)-C(sp3) cross-coupling of chlorobenzosulfonamides with alkyl Grignard reagents under mild and sustainable conditions. Electronically and sterically varied benzosulfonamides as well as challenging alkyl organometallics containing β-hydrogen afford alkylated benzosulfonamides in high to excellent yields. Sulfonamide represents the most reactive activating group for iron-catalyzed cross-coupling. The process affords alkylated benzenesulfonamides poised for medicinal chemistry applications and traceless reductive cleavage.

Amidrazones and their use as pesticides

This invention relates to amidrazones, insecticidal amidrazone compositions, and methods of using such compositions.