3335-29-3

Basic information

• Product Name: Piperidine, 1-[(4-chlorophenyl)thioxomethyl]-
• CAS NO: 3335-29-3
• Molecular Formula: C12H14ClNS
• Molecular Weight: 239.769
• Mol File: 3335-29-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Piperidine, 1-[(4-chlorophenyl)thioxomethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Piperidine, 1-[(4-chlorophenyl)thioxomethyl]-(3335-29-3)
• EPA Substance Registry System: Piperidine, 1-[(4-chlorophenyl)thioxomethyl]-(3335-29-3)

Safety Data

• Hazardous Substances Data: 3335-29-3(Hazardous Substances Data)

Upstream product

• 26163-40-6 N-(4-chlorobenzoyl)piperidine 
• 104-88-1 4-chlorobenzaldehyde 
• 2168-82-3 dithio-4-chlorobenzoic acid 
• 110-89-4 piperidine 
• 60410-79-9 bis<4-chloro(thiobenzoyl)> sulfide 

Downstream Products

• 120290-21-3 1-[(4-Chloro-phenyl)-methylsulfanyl-methyl]-piperidine 
• 104-88-1 4-chlorobenzaldehyde 
• 37932-45-9 3,6-bis-(4-chloro-phenyl)-[1,2,4,5]tetrazine 
• 50487-61-1 4-chlorothiobenzoylhydrazine 
• 26163-40-6 N-(4-chlorobenzoyl)piperidine 
• 120290-12-2 1-[(4-Chloro-phenyl)-methylsulfanyl-methylene]-piperidinium; iodide 
• 53876-70-3 3,6-bis-(4-chloro-phenyl)-1,4-dihydro-[1,2,4,5]tetrazine 

Relevant articles and documents

Willgerodt-Kindler reaction at room temperature: Synthesis of thioamides from aromatic aldehydes and cyclic secondary amines

A simple method for the synthesis of thioamide derivatives in DMSO at room temperature and at 120 °C has been developed. Total 27 compounds were prepared under both conditions via a one-pot, three component reaction between substituted aromatic aldehydes,

Facile preparation of amides from thioamides by ceric ammonium nitrate

Ceric ammonium nitrate (CAN) is found to be a good oxidizing agent which converts thioamides into their oxygen analogues in aqueous acetic acid under very mild conditions.

Preparation and Some Reactions of Bis(thioacyl) Sulfides

Reaction of dithioic acids with dicyclohexylcarbodiimide has been found to give the corresponding bis(thioacyl) sulfides 1 in good yield, which are very useful thioacylating reagents under mild reaction conditions.Most of the aromatic thioanhydrides (1, R = aromatic) are fairly stable green crystals at room temperature, but the aliphatic ones (1, R = aliphatic) are unstable purple oils which dimerize at room temperature to give the dithietanes 5.The reactions with nucleophiles are discussed.