3335-29-3

Basic information

• Product Name: Piperidine, 1-[(4-chlorophenyl)thioxomethyl]-
• CAS NO: 3335-29-3
• Molecular Formula: C12H14ClNS
• Molecular Weight: 239.769
• Mol File: 3335-29-3.mol

Chemical Properties

• CAS DataBase Reference: Piperidine, 1-[(4-chlorophenyl)thioxomethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Piperidine, 1-[(4-chlorophenyl)thioxomethyl]-(3335-29-3)
• EPA Substance Registry System: Piperidine, 1-[(4-chlorophenyl)thioxomethyl]-(3335-29-3)

Safety Data

• Hazardous Substances Data: 3335-29-3(Hazardous Substances Data)

Upstream product

• 104-88-1 4-chlorobenzaldehyde 
• 2168-82-3 dithio-4-chlorobenzoic acid 
• 26163-40-6 N-(4-chlorobenzoyl)piperidine 
• 110-89-4 piperidine 
• 60410-79-9 bis<4-chloro(thiobenzoyl)> sulfide 

Downstream Products

• 120290-12-2 1-[(4-Chloro-phenyl)-methylsulfanyl-methylene]-piperidinium; iodide 
• 120290-21-3 1-[(4-Chloro-phenyl)-methylsulfanyl-methyl]-piperidine 
• 104-88-1 4-chlorobenzaldehyde 
• 50487-61-1 4-chlorothiobenzoylhydrazine 
• 26163-40-6 N-(4-chlorobenzoyl)piperidine 
• 53876-70-3 3,6-bis-(4-chloro-phenyl)-1,4-dihydro-[1,2,4,5]tetrazine 
• 37932-45-9 3,6-bis-(4-chloro-phenyl)-[1,2,4,5]tetrazine 

Relevant articles and documents

Willgerodt-Kindler reaction at room temperature: Synthesis of thioamides from aromatic aldehydes and cyclic secondary amines

A simple method for the synthesis of thioamide derivatives in DMSO at room temperature and at 120 °C has been developed. Total 27 compounds were prepared under both conditions via a one-pot, three component reaction between substituted aromatic aldehydes,

ANTIFUNGAL AGENTS

Compounds of formula (I), and pharmaceutically acceptable salts thereof, may be used in therapy, for example as antifungal agents, wherein: R1, R2 and R3 are as defined herein. Certain compounds of formula (I) are also provided. Compounds of formula (I), and agriculturally acceptable salts thereof, may also be used as agricultural fungicides.

Facile preparation of amides from thioamides by ceric ammonium nitrate

Ceric ammonium nitrate (CAN) is found to be a good oxidizing agent which converts thioamides into their oxygen analogues in aqueous acetic acid under very mild conditions.

BADANIA W DZIEDZINIE TIOAMIDOW I ICH POCHODNYCH IX. SYNTEZA POCHODNYCH 1,2,4,5-TETRAZYNY

In reactions of N,N-disubstituted thioamides, derivatives of 4-thiobenzoylmorpholine, 1-thiobenzoylpiperidine and N1,N2-di(α-morpholinobenzylidene)azine, N1,N2-di(α-piperidinobenzylidene)azine also 4-(R-α-phenylaminobenzylidene)morpholinium and 1-(R-α-phenylaminobenzylidene)piperidinium iodides with hydrazine there was obtained a series compounds, derivatives of 1,2,4,5-tetrazine.Structures of obtained compounds have been determined by elemental analysis and on the ground of their UV and IR spectra.

Preparation and Some Reactions of Bis(thioacyl) Sulfides

Reaction of dithioic acids with dicyclohexylcarbodiimide has been found to give the corresponding bis(thioacyl) sulfides 1 in good yield, which are very useful thioacylating reagents under mild reaction conditions.Most of the aromatic thioanhydrides (1, R = aromatic) are fairly stable green crystals at room temperature, but the aliphatic ones (1, R = aliphatic) are unstable purple oils which dimerize at room temperature to give the dithietanes 5.The reactions with nucleophiles are discussed.

Preparation and Some Reactions of Phenylmercury Thio- and Dithiocarboxylates

It has been found that the reaction of diphenylmercury with an equimolar amount of thio- or dithio acids gave the corresponding phenylmercury thio- (1) or dithiocarboxylates (2), quantitatively, which further react with thio- or dithio acids to give mercury bis(thio-) (3) or bis(dithiocarboxylates) (4).The phenylmercury dithio salts (2) were found to be the very useful thioacylating agents for primary and secondary amines.The reaction of mercury bis(thiocarboxylates) (3) with dithiocarboxylic acids gave the unsymmetrical thio- and dithiocarboxylic acid mercury salts (5) in good yield. - Keywords: Phenylmercury Thiocarboxylates

Ovicidal and larvicidal cyanomethyl thioesters

There are provided novel cyanomethyl thioester compounds useful as ovicidal and larvicidal agents effective for the control of insects.

Infrared spectra of several thiopiperidides and thiomorpholides

Infrared spectra in the 1700-500 cm-1 region have been studied for several types of thiopiperidides (thiobenzoylpiperidides, thiocinnamoylpiperidides and phenylthioacetpiperidides) and for the corresponding thiomorpholides.Three characteristic thioamide bands were located and assigned.The behaviour of these bands on molecular complexing (with iodine as an electron acceptor) was used to support the assignments.The experimental data were discussed in terms of the theoretical results obtained by an HMO procedure.