334000-03-2Relevant academic research and scientific papers
Total syntheses of (±)-axamide-1 and (±)-axisonitrile-1 via 6-Exo-dig radical cyclization
Kuo, Yuan-Liang,Dhanasekaran, Manickam,Sha, Chin-Kang
supporting information; experimental part, p. 2033 - 2038 (2009/08/07)
Total syntheses of (±)-axamide-1 (1) and (±)-axisonitrile-1 (2) were accomplished by using the α-carbonyl radical cyclization as the key step. Thienylcyanocuprate 24 mediated conjugated addition of 5-(trimethylsilyl)-4-pentynylmagnesium chloride (23) to 3
A simple iodination protocol via in situ generated ICl using NaI/FeCl 3
Mohanakrishnan, Arasambattu K.,Prakash, Chandran,Ramesh, Neelamegam
, p. 3242 - 3247 (2007/10/03)
A novel iodination of silyl-enol ethers using hitherto unexplored NaI/FeCl3 system is reported. The procedure has been extended to the iodination of aromatic and hetero aromatic compounds.
Synthesis of β-substituted α-iodo cycloalkanones by the CuI-mediated conjugate addition of Grignard reagents to α-iodo cycloalkenones
Sha, Chin-Kang,Tseng, Chen-Tso,Chang, Wen-Sheng
, p. 683 - 685 (2007/10/03)
CuI-mediated conjugate addition of Grignard reagents to α-iodo cycloalkenones afforded β-substituted α-iodo cycloalkanones in good to excellent yields.
