334757-17-4

Upstream product

• 33877-11-1 (S)-1-mercapto-1-phenylethane 
• 146176-60-5 2,2,4,4-tetramethyl-1,3-oxazolidine-3-carbonyl chloride 
• 62258-06-4 thioacetic acid S-((S)-1-phenylethyl) ester 

Downstream Products

• 334757-24-3 (+)-(R)-S-(1-Benzoyl-1-phenylethyl)-(2,2,4,4-tetramethyl-1,3-oxazolidine-3-carbonylthiocarboxylate) 
• 334757-20-9 Methyl (-)-(R)-2-phenyl-2-(2,2,4,4-tetramethyl-1,3-oxazolidine-3-thio)propionate 
• 334757-21-0 (-)-(R)-2-Phenyl-2-(2,2,4,4-tetramethyl-1,3-oxazolidine-3-thio)-3-pentanone 
• 334757-23-2 (-)-(R)-4,4-Dimethyl-2-phenyl-2-(2,2,4,4-tetramethyl-1,3-oxazolidine-3-carbonylthio)-3-pentanone 
• 334757-32-3 (-)-(S)-S-1-Methyl-1-phenylpropyl 2,2,4,4-tetramethyl-1,3-oxazolidine-3-thiocarboxylate 
• 334757-47-0 (-)-(S)-S-1-[N-(2-Hydroxy-1,1-dimethylethyl)-aminocarbonylthio]-1-phenylethane 
• 334757-52-7 (-)-(R)-S-2-Hydroxy-1-methyl-1-phenylethyl 2,2,4,4-tetramethyl-1,3-oxazolidine-3-thiocarboxylate 
• 334757-39-0 (-)-(R)-S-2-[N-(2-Hydroxy-1,1-dimethylethyl)-aminocarbonylthio]-4-methyl-2-phenyl-3-pentanone 
• 334756-44-4 (-)-(R)-S-2-[N-(2-Hydroxy-1,1-dimethylethyl)-aminocarbonylthio]-2-phenyl-3-pentanone 

Relevant academic research and scientific papers

The configurational stability of an enantioenriched α-thiobenzyllithium derivative and the stereochemical course of its electrophilic substitution reactions; synthesis of enantiomerically pure, tertiary benzylic thiols

The lithium compound (S)-7, formed by deprotonation of the (S)-S-1-phenylethyl thiocarbamate (S)-10, is configurationally stable at -70°C. Even at elevated temperatures it racemizes only very slowly. It represents the first essentially enantiopure αthioca

A Highly Enantiomerically Enriched α-Thiobenzyl Derivative with Unusual Configurational Stability

Keywords: carbanions; chirality; configuration inversion; ion pairs; lithium