33877-11-1

Usage

Uses

Used in Flavoring Industry:
(S)-1-Phenylethanethiol is used as a flavoring agent in the food and beverage industry for its characteristic onion-like aroma, enhancing the taste and aroma profiles of various products.
Used in Perfumery:
In the perfume industry, (S)-1-Phenylethanethiol is utilized as a component in creating complex and nuanced fragrances, capitalizing on its distinct scent to contribute to the overall olfactory experience.
Used in Organic Synthesis:
(S)-1-Phenylethanethiol serves as a reagent in organic synthesis, playing a crucial role in the production of various organic compounds and contributing to the advancement of chemical research and development.

InChI:InChI=1/C8H10S/c1-7(9)8-5-3-2-4-6-8/h2-7,9H,1H3/t7-/m0/s1

Upstream product

• 52053-61-9 di(α-methylbenzyl)disulfide 
• 585-71-7 (1-bromoethyl)benzne 
• 98-86-2 acetophenone 
• 672-65-1 (1-chloroethyl)benzene 
• 32362-99-5 benzylthioacetate 
• 98-85-1 1-Phenylethanol 
• 64-04-0 phenethylamine 
• 33877-15-5 (R)-(+)-styrene sulfide 
• 54810-89-8 α-Isopropylamino-α-phenylpropionitril 
• 67385-07-3 S-(1-phenylethyl) ethanethioate 
• 64-19-7 acetic acid 
• 29850-82-6 (+/-)-(S)-(1-phenyl-ethyl)-isothiourea; hydrobromide 
• 124908-16-3 1-phenylethyl thiocyanate 
• 100-42-5 styrene 

Downstream Products

• 13125-70-7 (+-)-methyl-(1-phenyl-ethyl)-sulfide 
• 50999-18-3 racem.-bis-(1-phenyl-ethyl)-disulfide 
• 103-81-1 Benzeneacetamide 
• 67385-07-3 S-(1-phenylethyl) ethanethioate 
• 345927-66-4 (2,4-dinitro-phenyl)-(1-phenyl-ethyl)-sulfide 
• 20803-99-0 racemic 2-((1-phenylethyl)thio)acetic acid 
• 91970-39-7 2,4-Dimethyl-4-phenyl-3-thia-buttersaeure 
• 69543-90-4 α-Phenaethyl-thionitrit 
• 96418-50-7 S-<α-Methyl-benzylmercapto>-thioglykolsaeure-methylester 
• 69652-49-9 1-Phenaethyl-allylsulfid 
• 42383-85-7 C₉H₁₂N₂S₂ 
• 33691-99-5 1-(1-Phenyl-ethylsulfanyl)-propan-2-one 
• 113472-37-0 Methyl-phosphonodithioic acid S,S-bis-(1-phenyl-ethyl) ester 
• 113034-06-3 Phenyl-phosphonodithioic acid S,S-bis-(1-phenyl-ethyl) ester 

Relevant academic research and scientific papers

Accelerated reduction and solubilization of elemental sulfur by 1,2-aminothiols

Nucleophilic 1,2-aminothiol compounds readily reduce typically-insoluble elemental sulfur to polysulfides in both water and nonpolar organic solvents. The resulting anionic polysulfide species are stabilized through hydrogen-bonding interactions with the proximal amine moieties. These interactions can facilitate sulfur transfer to alkenes.

1-aryl ethanesulfonic acid and preparation method of its derivative

The invention provides 1-aryl ethanesulfonic acid and a preparation method of its derivative. The preparation method comprises the following steps that (a) 1-aryl halogensated ethane represented in aformula (I) and sodium hydrosulfide react to generate 1-

Phosphorus pentasulfide mediated conversion of organic thiocyanates to thiols

In this paper we report an efficient and mild procedure for the conversion of organic thiocyanates to thiols in the presence of phosphorus pentasulfide (P2S5) in refluxing toluene. The method avoids the use of expensive and hazardous transition metals and harsh reducing agents, as required by reported methods, and provides an attractive alternative to the existing methods for the conversion of organic thiocyanates to thiols.

Ligand dependence of the synthetic approach and chiroptical properties of a magic cluster protected with a bicyclic chiral thiolate

Chiral gold clusters stabilised by enantiopure thiolates were prepared, size-selected and characterised by circular dichroism and mass spectrometry. The product distribution is found to be ligand dependent. Au25 clusters protected with camphorthiol show clear resemblance of their chiroptical properties with their glutathionate analogue. The Royal Society of Chemistry 2012.

Dutch Resolution: Separation of enantiomers with families of resolving agents. A status report

Dutch Resolution is the term given to the use of mixtures (families) of resolving agents in classical resolutions. In this status report an overview is given of the latest results and new (possible) families of resolving agents are introduced. The concept of families is discussed as well as the factors that come into play on use of families. Practical aspects of Dutch Resolution in particular and resolutions in general are discussed.

Flavour and fragrance compositions

Flavour and fragrance compositions comprising 1-mercapto-1-arylalkanes or derivatives thereof.

Highly enantioselective reaction of α-lithio 2-quinolyl sulfide using chiral bis(oxazoline)s: A new synthesis of enantioenriched thiols

The enantioselective reaction of α-lithio benzyl 2-quinolyl sulfide proceeds through a dynamic thermodynamic resolution pathway, giving the products with high stereoselectivity. The products afford chiral thiols without racemization upon removal of the quinolyl group. Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002.

The configurational stability of an enantioenriched α-thiobenzyllithium derivative and the stereochemical course of its electrophilic substitution reactions; synthesis of enantiomerically pure, tertiary benzylic thiols

The lithium compound (S)-7, formed by deprotonation of the (S)-S-1-phenylethyl thiocarbamate (S)-10, is configurationally stable at -70°C. Even at elevated temperatures it racemizes only very slowly. It represents the first essentially enantiopure αthioca

A general and mild synthesis of thioesters and thiols from halides

The conversion of a wide variety of halides to thioesters by reaction with potassium thiocetate under mild conditions is described, and the generality of the method is demonstrated.

A Highly Enantiomerically Enriched α-Thiobenzyl Derivative with Unusual Configurational Stability

Keywords: carbanions; chirality; configuration inversion; ion pairs; lithium