33509-94-3

Basic information

• Product Name: Ethanone, 1-(4-methoxyphenyl)-2-(2-methylphenyl)-
• CAS NO: 33509-94-3
• Molecular Formula: C16H16O2
• Molecular Weight: 240.302
• Mol File: 33509-94-3.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Ethanone, 1-(4-methoxyphenyl)-2-(2-methylphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-(4-methoxyphenyl)-2-(2-methylphenyl)-(33509-94-3)
• EPA Substance Registry System: Ethanone, 1-(4-methoxyphenyl)-2-(2-methylphenyl)-(33509-94-3)

Safety Data

• Hazardous Substances Data: 33509-94-3(Hazardous Substances Data)

Upstream product

• 644-36-0 o-methylphenylacetic acid 
• 100-66-3 methoxybenzene 
• 10166-09-3 (o-tolyl)acetyl chloride 
• 95-49-8 2-methylchlorobenzene 
• 3319-15-1 rac-1-(4-methoxyphenyl)-ethanol 
• 100-06-1 1-(4-methoxyphenyl)ethanone 
• 95-46-5 2-methylphenyl bromide 

Downstream Products

• 114583-95-8 1-(4-methoxyphenyl)-2-(2-methylphenyl)-3-(3-methoxyphenyl)-1-propanone 
• 114584-00-8 2-(2-methylphenyl)-3-(4-methoxyphenyl)-6-methoxyindene 
• 114584-08-6 2-(2-methylphenyl)-3-(4-hydroxyphenyl)-6-hydroxyindene 
• 136667-15-7 2-(p-methoxyphenyl)-2-indanol 

Relevant articles and documents

Method for preparing substituted aryl ketone by ketone arylation (by machine translation)

The invention provides a method, for preparing substituted aryl ketone, by using a nitrogen heterocyclic carbene catalyst, with a saturated nitrogen heterocyclic carbene structure in an oxygen-containing atmosphere at, through α - catalysis of a nitrogen heterocyclic carbene structure, in a nitrogen heterocyclic carbene catalyst with a saturated nitrogen heterocyclic carbene structure under an alkaline condition, in an oxygen-containing atmosphere and can efficiently prepare various substituted, aryl ketones α - under the condition of containing an oxygen. atmosphere. (by machine translation)

N-heterocyclic carbene adducts of cyclopalladated ferrocenylpyridazine: Synthesis, structural characterization, and application in α-arylation of ketones with aryl chlorides

A new ferrocene-based ligand 3-chloro-6-pyridazinylferrocene 1 and its N-heterocyclic carbene adducts 2-3 were synthesized and characterized by 1H NMR and IR spectroscopy, ESI-MS, and elemental analysis. Additionally, detailed structures of complexes 2-3 have been determined by single-crystal X-ray analysis. Complex 3 exhibited high catalytic activity for α-arylation of ketones with aryl chlorides. Typically, using 1mol% catalyst in the presence of 1.5 equivalents of tBuOK as base in dioxane at 100°C provided coupled products in good yields.

(N-Heterocyclic Carbene)-Pd-catalyzed anaerobic oxidation of secondary alcohols and domino oxidation-arylation reactions

The use of commercially available (SIPr)Pd(cinnamyl)Cl (SIPr = 1,3-bis(2,6-diisopropylphenyl)-4,5-dihydroimidazol-2-ylidene) as a precatalyst for the anaerobic oxidation of secondary alcohols is described. The use of this complex allows for a drastic reduction in the reaction times and catalyst loading when compared to the unsaturated counterpart. This catalytic system is compatible with the use of microwave dielectric heating, decreasing even further catalyst loading and reaction times. Domino Pd-catalyzed oxidation-arylation reactions of secondary alcohols are also presented.(Figure Presented)