3358-25-6Relevant academic research and scientific papers
Wittig Ylide Mediated Decomposition of N -Sulfonylhydrazones to Sulfinates
Choudhary, Deepika,Khatri, Vineeta,Basak, Ashok K.
supporting information, p. 1703 - 1706 (2018/04/14)
N-Sulfonylhydrazones generate sulfinates selectively when treated with a stabilized Wittig ylide in a polar aprotic solvent at elevated temperature. The transition metal and base free decomposition method is applicable to N-sulfonylhydrazones generated from a number of aromatic and heteroaromatic aldehydes and ketones. In the case of N-tosylhydrazones derived from O-allyl and O-propargyl salicylaldehydes, selective formation of sulfinate occurs over intramolecular [3 + 2]-cycloaddition reaction.
Surface photochemistry: generation of benzyl radical pairs on dry silica gel
Frederick, Bradley,Johnston, Linda J.,Mayo, Paul de,Wong, S. King
, p. 403 - 410 (2007/10/02)
Singlet and triplet benzyl radical pairs have been generated on silica gel by photolysis of a benzyl phenylacetate, a dibenzyl ketone, and a dibenzyl sulfone.The extent of geminate radical recombination has been measured and requires that translational motion of radicals occur on the silica gel surface.This motion was affected by the radical pair multiplicity and the photolysis temperature, but was relatively insensitive to the state of hydration of the silica gel and presence of coadsorbates.The presence of certain rearranged starting materials, which are not formed in solution , amongst the products from photolysis of both dibenzyl ketone and dibenzyl sulfone on silica gel indicates the restrictions on radical movement on the surface on the shorter timescale of the benzyl-phenylacetyl and -benzyl - benzyl sulfonyl radical pairs.
