620-32-6Relevant articles and documents
Henriques,Margnetti
, p. 476,477 (1946)
Catalytic Activity of Polyfunctional Ionic Liquids in Oxidation of Model Sulfur Organic Compounds
Akopyan,Eseva,Polikarpova,Baigil’diev,Rodin,Anishnov
, p. 569 - 575 (2019)
Ionic liquids having acid centers in the imidazolium cation and molybdenum, tungsten, and vanadium atoms in the anion were synthesized and their catalytic activity in the oxidation of organosulfur compounds was examined. The highest catalytic activity is exhibited by the ionic liquid containing a molybdenum atom. The infl uence exerted by the reaction duration and by the amount of the ionic liquid and oxidizing agent on the conversion of methyl phenyl sulfide. The conditions are found for reaching the 100% conversion of methyl phenyl sulfide under mild conditions in the presence of the catalysts, ionic liquids [ionic liquid: 3-(carboxymethyl)-1-methyl-1H-imidazol-3-ium molybdate with S: Mo molar ratio = 24 ∶ 1, 2 h, 40°C, H2O2: S molar ratio = 12 ∶ 1]. The efficiency of using polyfunctional catalysts based on ionic liquids containing a Br?nsted acid center in the cation for oxidation of organosulfur compounds as compared with application of a simple mixture of an ionic liquid and a transition metal salt.
Magneli-type tungsten oxide nanorods as catalysts for the selective oxidation of organic sulfides
D?ren, René,Hartmann, Jens,Leibauer, Benjamin,Panth?fer, Martin,Mondeshki, Mihail,Tremel, Wolfgang
, p. 14027 - 14037 (2021/10/19)
Selective oxidation of thioethers is an important reaction to obtain sulfoxides as synthetic intermediates for applications in the chemical industry, medicinal chemistry and biology or the destruction of warfare agents. The reduced Magneli-type tungsten oxide WO3?xpossesses a unique oxidase-like activity which facilitates the oxidation of thioethers to the corresponding sulfoxides. More than 90% of the model system methylphenylsulfide could be converted to the sulfoxide with a selectivity of 98% at room temperature within 30 minutes, whereas oxidation to the corresponding sulfone was on a time scale of days. The concentration of the catalyst had a significant impact on the reaction rate. Reasonable catalytic effects were also observed for the selective oxidation of various organic sulfides with different substituents. The WO3?xnanocatalysts could be recycled at least 5 times without decrease in activity. We propose a metal oxide-catalyzed route based on the clean oxidant hydrogen peroxide. Compared to other molecular or enzyme catalysts the WO3?xsystem is a more robust redox-nanocatalyst, which is not susceptible to decomposition or denaturation under standard conditions. The unique oxidase-like activity of WO3?xcan be used for a wide range of applications in synthetic, environmental or medicinal chemistry.
A μ-AsO4-Bridging Hexadecanuclear Ni-Substituted Polyoxotungstate
Lian, Chen,Li, Hai-Lou,Yang, Guo-Yu
, p. 3996 - 4003 (2021/04/07)
A novel tetrahedral μ-AsO4-bridging hexadecanuclear Ni-substituted silicotungstate (ST) Na21H10[(AsO4){Ni8(OH)6(H2O)2(CO3)2(A-α-SiW9O34)2}2]·60H2O (1) was made by the reactions of trivacant [A-α-SiW9O34]10- ({SiW9}) units with Ni2+ cations and Na3AsO4·12H2O and characterized by IR spectrometry, elemental analysis, thermogravimetric analysis (TGA), and powder X-ray diffraction (PXRD). 1 contains a novel polyoxoanion [(AsO4){Ni8(OH)6(H2O)2(CO3)2(A-α-SiW9O34)2}2]31- built by four trivacant Keggin [A-α-SiW9O34]10- fragments linked through an unprecedented [(AsO4){Ni8(OH)6(H2O)2(CO3)2}2]9+ cluster, where the tetrahedral AsO4 acts as an exclusively μ2-bridging unit to link multiple Ni centers; such a connection mode appears for the first time in polyoxometalate chemistry. Furthermore, the electrochemical and catalytic oxidation properties of compound 1 have been investigated.
