33586-26-4Relevant academic research and scientific papers
Reaction of Thiolo and Seleno Esters of Phosphorus Acids with Halogens. 1. Stereochemical and 31P NMR Studies of Reaction of S-Methyl tert-Butylphenylphosphinothiolate with Elemental Chlorine and Sulfuryl Chloride
Krawiecka, B.,Michalski, J.,Wojna-Tadeusiak, E.
, p. 4201 - 4208 (1986)
Reaction of S-methyl tert-butylphenylphosphinothiolate (4) with elemental chlorine and sulfuryl chloride involves chlorolysis of the P-S bond and formation of the tert-butylphenylphosphinochloridate 5.It is demonstrated here that the stereoselectivity of
New procedures for the resolution of chiral tert-butylphenylphosphine oxide and some of its reactions
Drabowicz, Joezef,Lyzwa, Piotr,Omelanczuk, Jan,Pietrusiewicz, K. Michal,Mikolajczyk, Marian
, p. 2757 - 2763 (2007/10/03)
Racemic t-butylphenylphosphine oxide was resolved via formation of diastereoisomeric complexes with (+)-(R)-1,1'-binaphthalene-2,2'-diol and (+)-(S)-mandelic acid. With the latter complexing agent, separation of the essentially enantiopure (-)-(S)-enantio
