Reaction of Thiolo and Seleno Esters of Phosphorus Acids with Halogens. 1. Stereochemical and 31P NMR Studies of Reaction of S-Methyl tert-Butylphenylphosphinothiolate with Elemental Chlorine and Sulfuryl Chloride

DOI: 10.1021/jo00372a019

Source and publish data:

Journal of Organic Chemistry p. 4201 - 4208 (1986)

Update date:2022-08-30

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Authors:

Krawiecka, B.

Michalski, J.

Wojna-Tadeusiak, E.

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Article abstract of DOI:10.1021/jo00372a019

Reaction of S-methyl tert-butylphenylphosphinothiolate (4) with elemental chlorine and sulfuryl chloride involves chlorolysis of the P-S bond and formation of the tert-butylphenylphosphinochloridate 5.It is demonstrated here that the stereoselectivity of

Full text of DOI:10.1021/jo00372a019

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