33715-26-3Relevant academic research and scientific papers
Aminocatalytic asymmetric Diels-Alder reaction of phosphorus dienophiles and 2,4-dienals
Zhou, Qing-Qing,Yuan, Xin,Xiao, You-Cai,Dong, Lin,Chen, Ying-Chun
, p. 10369 - 10374 (2013)
Chiral compounds bearing a phosphorus functional group are valuable because of their wide application in biological studies and asymmetric catalysis. Here we present an asymmetric Diels-Alder cycloaddition between phosphor-containing dienophiles and 2,4-d
Design, synthesis and biological evaluation of peptidyl- vinylaminophosphonates as novel cysteine protease inhibitors
Bhattacharya, Asish K.,Rana, Kalpeshkumar C.
, p. 7129 - 7135 (2012/02/02)
We report herein, design and synthesis of vinylaminophosphonates, a novel class of compounds as possible cysteine protease inhibitors. The synthesis of vinylaminophosphonates has been accomplished employing Tsuji-Trost reaction as a key step. The synthesi
Cyclo-ruthenated and -platinated complexes bearing phosphonate substituents
Wadman, Sipke H.,Tooke, Duncan M.,Spek, Anthony L.,van Klink, Gerard P.M.,van Koten, Gerard
experimental part, p. 1701 - 1706 (2010/08/22)
Two new, potentially cyclometalating terdentate ligands bearing phosphonate substituents, Et2O3P-N^C(H)^N (5) and Et2O3P-C(H)^N^N (7), have been prepared. The corresponding ruthenium complexes, [1]+ and [2]+, respectively, were obtained by reaction with [RuCl3(tpy)]. Complexes [1]+ and [2]+ display electronic properties characteristic for cyclometalated ruthenium complexes. The platinum complex [3], of N^C(H)^N ligand 5, was also prepared and is highly phosphorescent in solution. In general, the phosphonate group electronically behaves equivalent to a carboxylate moiety.
