3376-25-8

Upstream product

• 4383-25-9 N-benzylcyclohexylamine 
• 100-39-0 benzyl bromide 
• 100-52-7 benzaldehyde 
• 2211-64-5 N-cyclohexyl-hydroxylamine 

Downstream Products

• 71504-40-0 2-cyclohexyl-4,4-dimethyl-3-phenyl-isoxazolidin-5-one 
• 1010707-57-9 C₁₆H₂₃NO 
• 17451-18-2 (Z)-2-benzoyl-3-phenylacrylic acid ethyl ester 
• 39626-31-8 ethyl (2E)-2-benzoyl-3-phenylacrylate 
• 138622-86-3 (3S,4S)-2-Cyclohexyl-3,4-diphenyl-1-oxa-2,5-diaza-spiro[5.5]undecan-5-ol 
• 1759-68-8 N-benzoylcyclohexylamine 
• 55041-10-6 1-cyclohexyl-2,4,5-triphenyl-1H-imidazole 
• 117644-93-6 2-cyclohexyl-4-ethoxycarbonyl-3-phenyl-4-isoxazoline 
• 117644-96-9 2-cyclohexyl-5-ethoxycarbonyl-3-phenyl-4-isoxazoline 
• 117644-92-5 2-cyclohexyl-4-methoxycarbonyl-3-phenyl-4-isoxazoline 
• 117644-95-8 2-cyclohexyl-5-methoxycarbonyl-3-phenyl-4-isoxazoline 
• 100617-63-8 N-benzyl-N-cyclohexyl-hydroxylamine 

Relevant academic research and scientific papers

REGULATORS FOR CONTROLLING LINEAR AND PSEUDO-RING EXPANSION POLYMERIZATION OF VINYL MONOMERS

The invention concerns new regulator compounds for a novel polymerization process for vinyl monomers, which yields polymers with improved control over composition and nearly full to full conservation of architectural integrity up to high conversion. The regulator compounds are defined by according to anyone of the Formulas (1A), (1B), (1C), (1D), (1E), (1F), (1G), (1H) and (1I), wherein R1 stands for an optionally substituted secondary or tertiary alkyl or secondary or tertiary aralkyl; Z1 stands for -CN or a carboxylic acid ester of formula C(O)OR21; Z2 may be chosen from the group of -CN, carboxylic acid, salts of carboxylic acids, carboxylic acid ester, carboxylic acid amides, (hetero)aryl, alkenyl and halogen; R2, R3, R4 and R5 are each independently chosen from the group of H, alkyl, aralkyl, (hetero)aryl, -CN and carboxylic acid ester of formula C(O)OR22; R7 stands for a primary alkyl or primary aralkyl, -CN or hydrogen; Y stands for a bridging group and n is 2, 3, 4, 5 or 6; in case R1 stands for tertiary alkyl or tertiary aralkyl, R6 stands for a primary alkyl or primary aralkyl, -CN or a carboxylic acid ester of formula C(O)OR26; in case R1 stands for a secondary alkyl or secondary aralkyl, R6 stands for a primary or secondary alkyl or primary or secondary aralkyl, -CN, a carboxylic acid ester of formula C(O)OR26 or a phosphonic acid ester of formula P(O)(OR27)2, a (hetero)aryl or an alkenyl; R21, R22, R26 and R27 each independently stand for alkyl or aralkyi having from 1-30 carbon atoms, optionally containing heteroatoms.

Organotin-oxotungstate coordination polymer: An efficient catalyst for the selective oxidation of amines

The organometallic coordination polymer [(nBu3Sn)2WO4] catalyzed the selective oxidation of secondary and primary amines to nitrones and oximes, respectively. The catalyst was found to be reusable for five catalytic cycles without any appreciable loss in activity. Under the optimized reaction conditions [4 mol% catalyst, 3-4 equiv of hydrogen peroxide (30 wt%, aqueous solution), methanol as the solvent, r.t.], the corresponding nitrones and oximes were obtained with good efficiency.