3376-38-3

Basic information

• Product Name: Cyclohexanone O-ethyl oxime
• Synonyms: Cyclohexanone O-ethyl oxime
• CAS NO: 3376-38-3
• Molecular Formula: C₈H₁₅NO
• Molecular Weight: 0
• Mol File: 3376-38-3.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclohexanone O-ethyl oxime(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone O-ethyl oxime(3376-38-3)
• EPA Substance Registry System: Cyclohexanone O-ethyl oxime(3376-38-3)

Safety Data

• Hazardous Substances Data: 3376-38-3(Hazardous Substances Data)

Upstream product

• 1122-60-7 1-nitrocyclohexane 
• 524-38-9 N-hydroxyphthalimide 
• 1914-21-2 N-ethoxyphthalimide 
• 108-94-1 cyclohexanone 
• 3332-29-4 O-ethylhydroxylamine hydrochloride 
• 100-64-1 cyclohexanone-oxime 
• 64-67-5 diethyl sulfate 

Downstream Products

• 31376-94-0 2-Bromcyclohexanonoxim-O-aethylaether 

Relevant articles and documents

Iridium-Catalyzed Unreactive C(sp3)-H Amination with 2,2,2-Trichloroethoxycarbonyl Azide

An additive-assisted iridium-catalyzed directed C(sp3)-H amination with 2,2,2-trichloroethoxycarbonyl azide as an amino source is reported. Both carboxylate anions and the corresponding cations in the additives are crucial to achieve satisfactory efficiency. Sodium acetate or n-pentanoic acid can promote the amination of various primary C(sp3)-H bonds adjacent to secondary, tertiary, and quaternary carbons in ketoximes or N-aromatic heterocycles, respectively, providing a practical route to versatile β-amino ketoxime and N-heteroaryl ethanamine derivatives. The amination products can be treated as isocyanate analogues and can be converted to other useful amino functionalities. An iridacyclic compound was isolated and identified as a plausible intermediate.