3378-45-8

Basic information

• Product Name: Dicyclohexyldiazene 1,2-dioxide
• Synonyms: Dicyclohexyldiazene 1,2-dioxide
• CAS NO: 3378-45-8
• Molecular Formula: C₁₂H₂₂N₂O₂
• Molecular Weight: 0
• Mol File: 3378-45-8.mol
• Article Data: 9

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Dicyclohexyldiazene 1,2-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: Dicyclohexyldiazene 1,2-dioxide(3378-45-8)
• EPA Substance Registry System: Dicyclohexyldiazene 1,2-dioxide(3378-45-8)

Safety Data

• Hazardous Substances Data: 3378-45-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C12H22N2O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h11-12H,1-10H2

Upstream product

• 110-82-7 cyclohexane 
• 2211-64-5 N-cyclohexyl-hydroxylamine 
• 1122-60-7 1-nitrocyclohexane 
• 75-52-5 nitromethane 
• 108-91-8 cyclohexylamine 
• 67-64-1 acetone 

Downstream Products

• 100-64-1 cyclohexanone-oxime 
• 54978-08-4 N-(1-Chloro-cyclohexyl)-N'-cyclohexyl-diazene N-oxide 
• 1781-74-4 (Z)-Dicyclohexyldiazen-1-oxid 
• 57497-35-5 (Z)-Methylcyclohexyldiazen-1-oxid 
• 35214-90-5 (Z)-Cyclohexylmethyldiazen-1-oxid 

Relevant articles and documents

Photochemical Flow Oximation of Alkanes

The nitrosation of several alkanes using tert-butyl nitrite has been performed in flow showing a remarkable reduction in the reaction time compared with batch processing. Due to the necessity for large excesses of the alkane component a continuous recycling process was devised for the preparation of larger quantities of material.

Methyltrioxorhenium-Catalyzed Oxidation of Secondary and Primary Amines with Hydrogen Peroxide

The methyltrioxorhenium-catalyzed oxidation of secondary amines and primary amines with hydrogen peroxide has been carried out. The oxidation of secondary amines afforded nitrones in good-to-excellent yield. Benzylamines were selectively oxidized to oximes, while general primary alkylamines possessing the α-C -H bond gave mixtures of oximes, nitroso dimers, and azoxy compounds.

OXIDATION OF PRIMARY ALIPHATIC AMINES WITH SODIUM PERBORATE

A biphasic system of ethyl acetate and water containing sodium perborate, sodium bicarbonate and N,N,N',N'-tetraacetylethylenediamine oxidizes primary aliphatic amines to aliphatic C-nitroso compounds in good to excellent yields.