33815-65-5Relevant academic research and scientific papers
New arylaziridinyldifluoroborates: Useful Suzuki-Miyaura reagents
Luisi, Renzo,Giovine, Arianna,Florio, Saverio
supporting information; experimental part, p. 2683 - 2687 (2010/06/17)
Blossoming promises fruit! A new class of shelf stable organoboron reagents has been obtained from ortho- and laterally lithiated aziridines and benzylamines. Their usefulness as Suzuki-Miyaura reagents has been investigated, proving that they could be fruitful reagents for the preparation of arylated aziridines and benzylamines, even in enantioenriched form, and promising new bifunctional Lewis pairs for catalysis or small-molecule binding. (Chemical Equation Presented)
Lithiation of N-alkyl-(o-tolyl)aziridine: Stereoselective synthesis of isochromans
Dammacco, Mariangela,Degennaro, Leonardo,Florio, Saverio,Luisi, Renzo,Musio, Biagia,Altomare, Angela
supporting information; experimental part, p. 6319 - 6322 (2009/12/08)
(Chemical Equation Presented) The lithiation reaction of o-tolylaziridine 1 has been investigated by using the aziridine ring capability to act as a directing metalation group. Trapped with electrophiles, the resulting o-aziridinyl benzyllithium 1-Li give
