33818-56-3Relevant academic research and scientific papers
A mild electroassisted synthesis of (hetero)arylphosphonates
Sengmany, Stéphane,Ollivier, Anthony,Le Gall, Erwan,Léonel, Eric
supporting information, p. 4495 - 4500 (2018/06/29)
The electrochemically-assisted synthesis of (hetero)arylphosphonates from (hetero)aryl halides and dimethyl phosphite is described. Very mild and simple conditions are employed as the cross-coupling is carried out in galvanostatic mode, in an undivided ce
Probing the reactivity of H-phosphonate derivatives for the hydrophosphonylation of various alkenes and alkynes under free-radical conditions
Geant, Pierre-Yves,Mohamed, Bemba Sidi,Périgaud, Christian,Peyrottes, Suzanne,Uttaro, Jean-Pierre,Mathé, Christophe
, p. 5318 - 5324 (2016/07/06)
Hydrophosphonylation is an efficient process to create carbon-phosphorus bonds from unsaturated C-C bonds and to give rise to alkylphosphonate or vinylphosphonate derivatives. In this work, we report on the reactivity of H-phosphonate derivatives for the hydrophosphonylation of various alkenes and alkynes under photoinduced free-radical conditions. The reaction was carried out on activated, unactivated and/or disubstituted alkenes or alkynes with 2,2-dimethoxy-2-phenylacetophenone as a photoinitiator under UV irradiation.
A new synthesis of π-electron conjugated phosphonates and phosphonic bis(diethylamides) and their SHG activities
Ogawa, Takuji,Usuki, Naoya,Ono, Noboru
, p. 2953 - 2958 (2007/10/03)
A series of vinylic and arylic phosphonates and phosphonic bis(diethylamides) were prepared by copper promoted substitution of the corresponding bromides. These π-electron conjugated phosphonates and phosphonic bis(diethylamides) were investigated to eluc
