33832-15-4Relevant articles and documents
The structure of 1,2 cyclohexanedione photoproduct. II
Okada,Fujimoto,Nakano,et al.
, p. 2406 - 2408 (1976)
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Method for synthesizing cyclohexyl-modified cucurbit urils
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Paragraph 0024-0026, (2019/11/25)
The invention discloses a method for synthesizing cyclohexyl-modified cucurbit urils. The method comprises the steps: using 1,2-cyclohexanedione semihydrate, performing acidification by using H2SO4, HNO3, HCl and other inorganic acids or organic acids in water, performing a reaction on 1,2-cyclohexanedione semihydrate and urea so as to synthesize cyclohexyl-modified glycoluril, and further performing a reaction with paraformaldehyde so as to synthesize cyclohexyl-modified glycoluril diether and the fully-substituted cyclohexyl cucurbit urils. Characterization is carried out by means of X-ray single crystal diffraction, H MNR and the like. The method is simple, and has easy operation, the defects of cumbersome reaction steps, low reaction yield, environmental pollution and high cost of an original method can be overcome, the toxicity of selenium dioxide in the cucurbit urils is avoided, pollution is reduced, and the yield is improved.