33968-37-5Relevant academic research and scientific papers
Co2( CO)8-Catalyzed reaction of aromatic aldehydes with hydrosilanes under carbon monoxide as 1 atm: Incorporation of CO into the carbonyl carbon atom of aldehydes
Chatani, Naoto,Tokuhisa, Hideo,Kokubu, Ichiro,Fujii, Satoru,Murai, Shinji
, p. 193 - 198 (2007/10/02)
Co2(CO)8-catalyzed reaction of aromatic aldehydes with hydrosilanes under CO as 1 atm results in incorporation of CO into the carbonyl carbon atom of aldehydes to give arylethane-1,2-diol disilyl ethers as the main product.The reaction of aliphatic aldehydes gives similar products, only with low yields.Keywords: Cobalt; Silicon; Hydrosilane; Aldehyde; Carbon monoxide; Oxymethylation
