34025-26-8

Basic information

• Product Name: 2-(dimethyl-λ⁴-sulfaneylidene)-1,3-diphenylpropane-1,3-dione
• Synonyms: 2-(dimethyl-λ⁴-sulfaneylidene)-1,3-diphenylpropane-1,3-dione
• CAS NO: 34025-26-8
• Molecular Weight: 284.379
• Mol File: 34025-26-8.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 2-(dimethyl-λ⁴-sulfaneylidene)-1,3-diphenylpropane-1,3-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(dimethyl-λ⁴-sulfaneylidene)-1,3-diphenylpropane-1,3-dione(34025-26-8)
• EPA Substance Registry System: 2-(dimethyl-λ⁴-sulfaneylidene)-1,3-diphenylpropane-1,3-dione(34025-26-8)

Safety Data

• Hazardous Substances Data: 34025-26-8(Hazardous Substances Data)

Upstream product

• 75-18-3 dimethylsulfide 
• 120-46-7 1,3-diphenylpropanedione 
• 5667-47-0 phenacyldimethylsulfonium bromide 
• 622-29-7 N-Benzylidenemethylamine 
• 3741-66-0 Ethyl benzoyl carbonate 
• 5633-34-1 (benzoylmethylene)dimethylsulfurane 
• 39095-38-0 N-dimethylsulfoniumsuccinimide chloride 
• 42052-51-7 3-hydroxy-1,3-diphenylpropan-1-one 
• 93-97-0 benzoic acid anhydride 
• 2085-31-6 2-diazo-1,3-diphenylpropane-1,3-dione 

Downstream Products

• 64942-61-6 2,2,4-tribenzoyl-5-phenyl-1,3-oxathiole 
• 100037-70-5 (2,4-Dibenzoyl-5-phenyl-[1,3]oxaselenol-2-yl)-phenyl-methanone 
• 643-75-4 1,3-diphenyl-propane-1,2,3-trione 
• 67-68-5 dimethyl sulfoxide 
• 120-46-7 1,3-diphenylpropanedione 
• 606-86-0 1,3,3-triphenylpropan-1-one 
• 28195-13-3 2-(methylthio)-1,3-diphenylpropane-1,3-dione 
• 25187-63-7 1,1-Diphenyl-2-benzoyl-2-methylmercapto-ethylen 

Relevant articles and documents

Rhodium-Catalyzed Synthesis of Sulfur Ylides via in Situ Generated Iodonium Ylides

A convenient strategy for the synthesis of sulfur ylides via rhodium-catalyzed coupling of in situ generated iodonium ylides with sulfides or sulfoxides has been developed. A wide range of sulfur ylides were obtained in moderate to good yields from inexpensive sulfur compounds and active methylene compounds with a short reaction time (MW, 5-10 min) or 12-16 h at rt. Furthermore, these sulfoxonium ylides were used as novel acceptor/acceptor carbenes for N-H insertion reactions.

Convenient synthesis of stable sulfur ylides by reaction of active methylene compounds with Corey-Kim reagent

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Synthesis of 1,3-Dicarbonyl Compounds by the Oxidation of 3-Hydroxycarbonyl Compounds with Corey-Kim Reagent

A new method for the preparation of various 1,3-dicarbonyl compounds is described.Oxidation of 3-hydroxycarbonyl compounds without substituent at C-2 position by the Corey-Kim reagent (N-chlorosuccinimide-dimethyl sulfide) afforded the stable dimethylsulfonium methylides, which on reductive desulfurization by zinc-acetic acid furnished the 1,3-dicarbonyl derivatives.On the other hand, the same treatment of 2-mono-, or 2,2-disubstituted 3-hydroxy-carbonyl compounds gave directly the corresponding 1,3-dicarbonyl analogous, respectively.