340320-92-5

Upstream product

• 273749-60-3 phenyl 4,6-O-(4-methoxybenzylidene)-1-thio-β-D-glucopyranoside 

Downstream Products

• 916154-04-6 ((2R,3R,4R)-4-((tert-butyldimethylsilyl)oxy)-3-((4-methoxybenzyl)oxy)-3,4-dihydro-2H-pyran-2-yl)methanol 
• 1440947-78-3 tert-butyl(((2S,3R,4R)-2-(iodomethyl)-6-methoxy-3-((4-methoxybenzyl)oxy)tetrahydro-2H-pyran-4-yl)oxy)dimethylsilane 
• 1440947-80-7 tert-butyl(((2S,3R,4R)-2-(iodomethyl)-6-methoxy-3-((4-methoxybenzyl)oxy)tetrahydro-2H-pyran-4-yl)oxy)dimethylsilane 
• 384346-98-9 methyl 3-O-tert-butyldimethylsilyl-4,6-O-p-methoxybenzylidene-2-deoxy-2-trifluoroacetamido-β-D-glucopyranoside 
• 40299-08-9 methyl 2-deoxy-2-trifluoroacetamido-β-D-glucopyranoside 
• 3946-01-8 methyl N-acetyl-β-D-glucosaminide 

Relevant academic research and scientific papers

Stereoselective synthesis of [13C]methyl 2-[15N]amino-2-deoxy-beta-D-glucopyranoside derivatives.

Efficient syntheses of three [13C]methyl 2-[15N]amino-2-deoxy-beta-D-glucopyranoside derivatives are described. Amination of the D-glucal with (saltmen)Mn(15N) proceeded with 11:1 stereoselectivity favoring the gluco configuration; subsequent methylation of the [15N]lactol using [13C]iodomethane and silver(I) oxide afforded the doubly labeled beta glucoside in high yield. This compound served as the common precursor for three [13C]methyl 2-[15N]aminoglucosides: (2-[15N]trifluoroacetyl-), (2-[15N]acetyl-), and (2-[15N]azido-). Selected heteronuclear coupling constants are reported.