34131-94-7Relevant academic research and scientific papers
Enantioselective synthesis of (+)-α-vetivone through the Michael reaction of chiral imines
Revial, Gilbert,Jabin, Ivan,Pfau, Michel
, p. 4975 - 4983 (2007/10/03)
(+)-α-Vetivone has been synthesised in nine steps. The absolute stereochemistry of the two stereogenic centres is controlled in the same key step involving the stereoselective Michael addition of a chiral imine of 4-isopropylidene-2-methylcyclohexanone to phenyl crotonate.
Electrophile-Initiated Cyclobutane Ring Cleavage of (+)-cis-3-Methylnopinone
Kato, Michiharu,Kamat, Vijayendra P.,Tooyama, Youichi,Yoshikoshi, Akira
, p. 1536 - 1538 (2007/10/02)
Electrophile-initiated cleavage reactions of the cyclobutane ring in (+)-cis-3-methylnopinone (2) were studied. (4R,6R)-(+)-1-Acetoxy-4-(1-acetoxy-1-methylethyl)-6-methyl-1-cyclohexene (10) of good optical purity was obtained in high yield on treatment of
