341519-80-0

Upstream product

• 180713-44-4 2-[(pivaloyloxy)methyl]benzaldehyde 
• 4301-14-8 acetylenemagnesium bromide 
• 3282-30-2 pivaloyl chloride 
• 341519-79-7 2-hydroxymethylbenzyl pivalate 

Downstream Products

• 328527-43-1 10-methoxy-10-[7-methoxy-3-(2-hydroxycarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 662723-09-3 7-methoxy-3-(2-pivaloyloxymethylphenyl)-1,5-heptadiyn-3-(E)-ene 
• 662723-08-2 7-methoxy-3-(2-pivaloyloxymethyl)-1,5-heptadiyne-3-ol 
• 662723-12-8 10-methoxy-10-[7-methoxy-3-(2-hydroxymethylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 662723-13-9 10-hydroxy-10-[7-methoxy-3-(2-hydroxymethylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 662723-15-1 10-hydroxy-10-[7-methoxy-3-(2-methoxycarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 662723-14-0 10-hydroxy-10-[7-methoxy-3-(2-hydroxycarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 662723-16-2 10-hydroxy-10-[7-methoxy-3-(2-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 662723-19-5 10-acetoxy-10-[7-methoxy-3-(2-methoxycarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 662723-11-7 10-methoxy-10-[7-methoxy-3-(2-pivaloyloxymethylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 662723-20-8 10-acetoxy-10-[7-methoxy-3-(2-N,N-dimethylaminocarbonylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 662723-10-6 10-hydroxy-10-[7-methoxy-3-(2-pivaloyloxymethylphenyl)hept-3-ene-1,5-diynyl]-10H-anthracen-9-one 
• 341519-82-2 2,2-dimethyl-propionic acid 2-{4-(tert-butyl-dimethyl-silanyl)-1-[3-hydroxy-3-(4-nitro-phenyl)-3-phenyl-prop-1-ynyl]-but-1-en-3-ynyl}-benzyl ester 
• 341519-91-3 2,2-dimethyl-propionic acid 2-{4-(tert-butyl-dimethyl-silanyl)-1-[3-methoxy-3-(4-nitro-phenyl)-3-phenyl-prop-1-ynyl]-but-1-en-3-ynyl}-benzyl ester 

Relevant academic research and scientific papers

Developments of enediyne model compounds generating biradicals with an enhanced radical character - Regulation of triggering devices

Development of enediyne model compounds generating biradicals with an enhanced radical character is described. These model compounds generate enyne-allenes under mild acidic conditions and the resulting biradicals showed potent DNA cleaving abilities.

Acid-catalyzed cycloaromatization of enediyne model compounds via enyne-allene intermediates

The synthesis of enediyne models which produce dehydrotoluene diradicals preferentially under acidic conditions by means of intramolecular participation of the carboxylic acid is described. To diminish an ionic character of diradicals, an electron-withdrawing group was introduced into the radical-forming carbon of the substrate.