34160-87-7

Upstream product

• 115260-52-1 (1S,4S)-4-Hydroxy-1,3-dimethyl-2-((E)-3-oxo-but-1-enyl)-cyclohex-2-enecarboxylic acid methyl ester 
• 115260-50-9 (1S,4S)-methyl 4-benzoyloxy-1,3-dimethyl-2-(3-oxo-1E-butenyl)-2-cyclohexene-1-carboxylate 
• 38405-15-1 (4aS,5S)-4,4a,5,6,7,8-hexahydro-5-hydroxy-1,4a-dimethylnaphthalen-2(3H)-one 
• 115260-42-9 (2S,4aS,5S)-2,3,4,4a,5,6,7,8-octahydro-1,4a-dimethyl-5-tetrahydropyranyloxy-2-naphthols 
• 1345041-40-8 C₁₉H₂₈O₅ 
• 115260-49-6 Benzoic acid (1S,4S)-4-methoxycarbonyl-2,4-dimethyl-3-(3-oxo-2-phenylselanyl-butyl)-cyclohex-2-enyl ester 
• 115260-48-5 (1S,4S)-methyl-4-benzoyloxy-1,3-dimethyl-2-(3-oxobutyl)-2-cyclohexenecarboxylate 
• 115260-47-4 (2S,4aS,6RS)-2,3,4,4a,5,6,7,8-octahydro-6-hydroxy-1,4a,6-trimethyl-5-oxo-2-naphthyl benzoate 
• 115260-44-1 (2S,4aS,5S)-2,3,4,4a,5,6,7,8-octahydro-1,4a-dimethyl-5-tetrahydropyranyloxy-2-naphthyl benzoate 
• 115260-46-3 (2S,4aS,6RS)-2,3,4,4a,5,6,7,8-octahydro-1,4a-dimethyl-5-oxo-2-naphthyl benzoate 
• 115260-45-2 (-)-(2S,4aS)-2,3,4,4a,5,6,7,8-octahydro-1,4a-dimethyl-5-oxo-2-naphthyl benzoate 
• 123505-35-1 Benzoic acid (2S,4aS,5S)-5-hydroxy-1,4a-dimethyl-2,3,4,4a,5,6,7,8-octahydro-naphthalen-2-yl ester 
• 115260-41-8 (4aS,5S)-4,4a,5,6,7,8-hexahydro-1,4a-dimethyl-5-tetrahydropyranyloxy-2(3H)-naphthalenone 
• 41722-49-0 (S)-1,4a-dimethyl-4,4a,7,8-tetrahydronaphthalene-2,5(3H,6H)-dione 

Downstream Products

• 24513-25-5 (+)-(7E,9E)-methyl trisporate B 
• 24504-14-1 (+)-(7E,9Z)-methyl trisporate B 
• 115304-68-2 (S)-1,3-Dimethyl-2-[(1E,3Z)-3-methyl-6-(2-methyl-[1,3]dioxolan-2-yl)-hexa-1,3-dienyl]-4-oxo-cyclohex-2-enecarboxylic acid methyl ester 
• 115304-69-3 (S)-1,3-Dimethyl-2-[(1E,3E)-3-methyl-6-(2-methyl-[1,3]dioxolan-2-yl)-hexa-1,3-dienyl]-4-oxo-cyclohex-2-enecarboxylic acid methyl ester 

Relevant academic research and scientific papers

New apocarotenoids and β-carotene cleavage in Blakeslea trispora

Mixed cultures of strains of opposite sex ("mated" cultures) of Blakeslea trispora contain trisporic acids and other apocarotenoids, some of which mediate the sexual responses of this fungus and other Mucorales. In mated cultures of the wild-type strains

TOTAL SYNTHESIS OF (+)-METHYL TRISPORATE B, FUNGAL SEX HORMONE

The enantioselective synthesis of (+)-methyl trisporates B (2 and 4) has been described.The chiral enedione 11, which was prepared by asymetric aldol condensation of the prochiral triketone 12, was converted to α-hydroxyketone 9 via the oxobenzoate 10.Cle