342790-12-9

Basic information

• Product Name: (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl
• Synonyms: (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl
• CAS NO: 342790-12-9
• Molecular Weight: 913.023
• Mol File: 342790-12-9.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl(CAS DataBase Reference)
• NIST Chemistry Reference: (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl(342790-12-9)
• EPA Substance Registry System: (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl(342790-12-9)

Safety Data

• Hazardous Substances Data: 342790-12-9(Hazardous Substances Data)

Upstream product

• 22104-03-6 1,1,3,3-tetraethyl-1,3-dihydroisoindol-2-yloxyl 
• 121393-39-3 5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II) 
• 85990-32-5 (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide 
• 75-03-6 ethyl iodide 
• 5558-78-1 2-phenyl-pentanenitrile 
• 607-01-2 ethyl-diphenyl-phosphane 
• 111-43-3 Dipropyl ether 
• 1234321-53-9 1,1,3,3-tetrabutylisoindolin-2-oxyl 
• 769-68-6 2-phenylbutanenitrile 

Relevant articles and documents

Room-temperature selective aliphatic carbon-carbon bond activation and functionalization of ethers by rhodium(II) porphyrin

Selective aliphatic carbon(α)-carbon(β) bond activation of ethers by (5,10,15,20-tetramesitylporphyrinato)rhodium(II) (Rh(tmp) (1)) was achieved at room temperature to yield corresponding rhodium porphyrin alkyls and the functionalized esters. Rh(tmp)OH was the proposed intermediate responsible for cleaving the C(α)-C(β) bond. The reaction is general for both straight- and branch-chain ethers.

Base-promoted, selective aliphatic carbon-carbon bond cleavage of ethers by rhodium(III) porphyrin complexes

Summary: Base-promoted, selective aliphatic carbon(α)carbon(β) bond activation (CCA) of ethers by (5,10,15,20tetramesitylporphyrinato) rhodium(III) iodide was achieved.

Activation of aliphatic carbon-carbon bonds of esters and amides by rhodium(II) porphyrin

Aliphatic carbon-carbon bonds of esters and amides were activated successfully with rhodium(II) porphyrin radical to give rhodium(III) porphyrin alkyls in moderate yields.