(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl

Base Information

Chemical Name:(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl
CAS No.:342790-12-9
Molecular Formula:C₅₈H₅₇N₄Rh
Molecular Weight:913.023
Hs Code.:

Synonyms:(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl

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Chemical Property of (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl

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Technology Process of (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl

There total 11 articles about (5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: 85990-32-5
(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) iodide

: 75-03-6
ethyl iodide

: 342790-12-9
(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl

Guidance literature:: With sodium tetrahydroborate; In sodium hydroxide; ethanol; suspn. of Rh complex in EtOH and soln. of NaBH4 in aq. NaOH were purged separately with N2 for 15 min; soln. of NaBH4 was added to suspn. of Rh complex; heated at 55°C for 1 h under Ar; cooled to room temp.; EtI was added; stirred overnight; CH2Cl2 and H2O added; extd. (CH2Cl2); washed (H2O); dried (MgSO4); filtered; evapd.; chromd. (silica gel, hexane/CH2Cl2, 10/1 to 5/1); recrystd.(CH2Cl2/hexane);
DOI:10.1016/j.jorganchem.2007.01.012

Reference yield: 62.0%

: 121393-39-3
5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

: 111-43-3
Dipropyl ether

: 342790-12-9
(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl

: 110-74-7
propyl methanoate

Guidance literature:: With water; tetraphenylphosphonium bromide; triphenylphosphine; potassium hydroxide; at 25 ℃; regioselective reaction; Inert atmosphere; Darkness;
DOI:10.1021/om200280w

Reference yield: 62.0%

: 121393-39-3
5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinate rhodium(II)

: 111-43-3
Dipropyl ether

: 342790-12-9
(5,10,15,20-tetra(2,4,6-trimethylphenyl)porphyrinato)rhodium(III) ethyl

Guidance literature:: With PPh₃; KOH; Ph₄PBr; In further solvent(s); under N2; in the dark; Rh compd. reacted with (C3H7)2O in presence of PPh3 (1 equiv.), KOH (10 equiv.), H2O (50 equiv.) and Ph4PBr (0.1 equiv.) at 25°C for 10 min;
DOI:10.1021/om200280w