34339-63-4

Upstream product

• 70075-39-7 (E)-3-((4R,5R)-2,2,5-Trimethyl-[1,3]dioxolan-4-yl)-propenal 
• 28194-35-6 3,4-dihydro-2-methoxy-6-methyl-2H-pyran 
• 95777-54-1 (S)-2-Methyl-3-((4S,5S)-2,2,5-trimethyl-[1,3]dioxolan-4-yl)-5-trimethylsilanyl-isoxazolidine 
• 200625-47-4 polyketomycin 
• 67-56-1 methanol 
• 122-04-3 4-nitro-benzoyl chloride 
• 136963-43-4 (4S,5R)-4,6-isopropylidenedioxy-4-p-toluenesulfonyloxyhexanal 
• 98-59-9 p-toluenesulfonyl chloride 

Downstream Products

• 33985-37-4 2,3,6-trideoxy-D-erythrose (2,4-dinitrophenyl)hydrazone 
• 142573-12-4 methyl 4-O-(3,4-O-benzylidene-α-L-arabinopyranosyl)-2,3,6-trideoxy-β-D-erythro-hexopyranoside 
• 142573-13-5 methyl 4-O-<3,4-O-benzylidene-2-O-(2,3,4-tri-O-benzyl-α-L-fucopyranosyl)-α-L-arabinopyranosyl>-2,3,6-trideoxy-β-D-erythro-hexopyranoside 

Relevant academic research and scientific papers

Polyketomycin, a new antibiotic from Streptomyces sp. MK277-AF1. II. Structure determination

A new antibiotic, polyketomycin, was isolated from the culture broth of Streptomyces sp. MK277-AF1. The structure was determined by various NMR spectroscopies, X-ray crystallographic analysis and degradation experiments.

Improved Synthesis of Secondary Hydroperoxides from Alcohols

Secondary hydroperoxides have been prepared from secondary alcohols by conversion of the alcohol into its mesylate and subsequent reaction with anhydrous hydrazine followed by hydrogen peroxide and sodium peroxide.

Synthesis of some trideoxy-D-hexoses and derivatives thereof from D-glucono-1,5-lactone

Enantiospecific syntheses of methyl 2,3,4-trideoxy-α-D- and β-D-glycero-hexopyranoside (10 and 11), methyl α-D- and β-D-amicetopyranoside (24 and 25), (2S)-1,2-hexanediol (36), (2S)-1,2,6-hexanetriol (37), and some derivatives thereof from D-glucono-1,5-lactone are described. Enantiospecific syntheses of methyl 2,3,4-trideoxy-α-D- and -β-D-glycero-hexopyranoside (10 and 11), methyl α-D- and β-D-amicetopyranoside (24 and 25), (2S)-1,2-hexanediol (36), (2S)-1,2,6-hexanetriol (37), and some derivatives thereof from D-glucono-1,5-lactone are described.

NITRONE CYCLOADDITIONS WITH VINYL SILANES: THE TOTAL SYNTHESIS OF DEOXYSUGARS.

The total synthesis of (+/-)-rhodinose (2) and benzoxocin 4, a model system for the glycosidic moiety of nogalomycin, are reported.The key transformation in each reaction sequence involves the cycloaddition of a nitrone with vinyltrimethylsilane to produc